FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3208749076> ?p ?o ?g. }

• W3208749076 endingPage "19077" @default.
• W3208749076 startingPage "19067" @default.
• W3208749076 abstract "Many synthetic polymers used to form polymer-brush films feature a main backbone with functional, oligomeric side chains. While the structure of such graft polymers mimics biomacromolecules to an extent, it lacks the monodispersity and structural purity present in nature. Here we demonstrate that side-chain heterogeneity within graft polymers significantly influences hydration and the occurrence of hydrophobic interactions in the subsequently formed brushes and consequently impacts fundamental interfacial properties. This is demonstrated for the case of poly(methacrylate)s (PMAs) presenting oligomeric side chains of different length (n) and dispersity. A precise tuning of brush structure was achieved by first synthesizing oligo(2-ethyl-2-oxazoline) methacrylates (OEOXMAs) by cationic ring-opening polymerization (CROP), subsequently purifying them into discrete macromonomers with distinct values of n by column chromatography, and finally obtaining poly[oligo(2-ethyl-2-oxazoline) methacrylate]s (POEOXMAs) by reversible addition-fragmentation chain-transfer (RAFT) polymerization. Assembly of POEOXMA on Au surfaces yielded graft polymer brushes with different side-chain dispersities and lengths, whose properties were thoroughly investigated by a combination of variable angle spectroscopic ellipsometry (VASE), quartz crystal microbalance with dissipation (QCMD), and atomic force microscopy (AFM) methods. Side-chain dispersity, or dispersity within brushes, leads to assemblies that are more hydrated, less adhesive, and more lubricious and biopassive compared to analogous films obtained from graft polymers characterized by a homogeneous structure." @default.
• W3208749076 created "2021-11-08" @default.
• W3208749076 creator A5012332151 @default.
• W3208749076 creator A5012335802 @default.
• W3208749076 creator A5015432408 @default.
• W3208749076 creator A5026137812 @default.
• W3208749076 creator A5038787375 @default.
• W3208749076 creator A5041738921 @default.
• W3208749076 creator A5065244580 @default.
• W3208749076 creator A5068821613 @default.
• W3208749076 creator A5075760560 @default.
• W3208749076 creator A5076695399 @default.
• W3208749076 creator A5081232383 @default.
• W3208749076 creator A5083684082 @default.
• W3208749076 date "2021-11-05" @default.
• W3208749076 modified "2023-10-02" @default.
• W3208749076 title "Dispersity within Brushes Plays a Major Role in Determining Their Interfacial Properties: The Case of Oligoxazoline-Based Graft Polymers" @default.
• W3208749076 cites W1974262428 @default.
• W3208749076 cites W1980085478 @default.
• W3208749076 cites W1983250328 @default.
• W3208749076 cites W1985393072 @default.
• W3208749076 cites W1985710997 @default.
• W3208749076 cites W1987636437 @default.
• W3208749076 cites W1992615890 @default.
• W3208749076 cites W2013456869 @default.
• W3208749076 cites W2024397939 @default.
• W3208749076 cites W2036414224 @default.
• W3208749076 cites W2044000481 @default.
• W3208749076 cites W2048419315 @default.
• W3208749076 cites W2058229406 @default.
• W3208749076 cites W2064035411 @default.
• W3208749076 cites W2065735911 @default.
• W3208749076 cites W2080814015 @default.
• W3208749076 cites W2084938745 @default.
• W3208749076 cites W2088643691 @default.
• W3208749076 cites W2110710720 @default.
• W3208749076 cites W2131817737 @default.
• W3208749076 cites W2134627870 @default.
• W3208749076 cites W2137872572 @default.
• W3208749076 cites W2139460522 @default.
• W3208749076 cites W2141148505 @default.
• W3208749076 cites W2153622624 @default.
• W3208749076 cites W2168554493 @default.
• W3208749076 cites W2172156072 @default.
• W3208749076 cites W2262885032 @default.
• W3208749076 cites W2265203886 @default.
• W3208749076 cites W2318020043 @default.
• W3208749076 cites W2338444201 @default.
• W3208749076 cites W2347029936 @default.
• W3208749076 cites W2523044930 @default.
• W3208749076 cites W2596434115 @default.
• W3208749076 cites W2596724733 @default.
• W3208749076 cites W2599989106 @default.
• W3208749076 cites W2621982759 @default.
• W3208749076 cites W2625213762 @default.
• W3208749076 cites W2626707323 @default.
• W3208749076 cites W2745239534 @default.
• W3208749076 cites W2752827896 @default.
• W3208749076 cites W2764097862 @default.
• W3208749076 cites W2772794643 @default.
• W3208749076 cites W2774278399 @default.
• W3208749076 cites W2779553298 @default.
• W3208749076 cites W2796274659 @default.
• W3208749076 cites W2801176499 @default.
• W3208749076 cites W2807377921 @default.
• W3208749076 cites W2884408118 @default.
• W3208749076 cites W2899862056 @default.
• W3208749076 cites W2911325239 @default.
• W3208749076 cites W2913300369 @default.
• W3208749076 cites W2955765349 @default.
• W3208749076 cites W2959312048 @default.
• W3208749076 cites W2971273696 @default.
• W3208749076 cites W2974215257 @default.
• W3208749076 cites W2989984014 @default.
• W3208749076 cites W3003793737 @default.
• W3208749076 cites W3027412953 @default.
• W3208749076 cites W3040658539 @default.
• W3208749076 cites W3048274609 @default.
• W3208749076 cites W3093888427 @default.
• W3208749076 cites W3126889152 @default.
• W3208749076 cites W3145429288 @default.
• W3208749076 cites W3166043447 @default.
• W3208749076 cites W4234859966 @default.
• W3208749076 doi "https://doi.org/10.1021/jacs.1c08383" @default.
• W3208749076 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34738797" @default.
• W3208749076 hasPublicationYear "2021" @default.
• W3208749076 type Work @default.
• W3208749076 sameAs 3208749076 @default.
• W3208749076 citedByCount "14" @default.
• W3208749076 countsByYear W32087490762022 @default.
• W3208749076 countsByYear W32087490762023 @default.
• W3208749076 crossrefType "journal-article" @default.
• W3208749076 hasAuthorship W3208749076A5012332151 @default.
• W3208749076 hasAuthorship W3208749076A5012335802 @default.
• W3208749076 hasAuthorship W3208749076A5015432408 @default.
• W3208749076 hasAuthorship W3208749076A5026137812 @default.
• W3208749076 hasAuthorship W3208749076A5038787375 @default.
• W3208749076 hasAuthorship W3208749076A5041738921 @default.

• next