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- W3208788730 abstract "A cyclometalated NHC-coordinated hydrido tantalum alkoxide was found to selectively react with CO2 to afford the genuine tantalum formate (NHC)(HCOO)Ta(ORF)3 with ORF = OC(CF3)2CH3. In the solid state, the presence of a κ2-O,O-formate moiety was established by single-crystal X-ray diffraction and ATR-IR spectroscopy, while NMR experiments and DFT modeling studies suggest that the κ1-O-coordination mode is preferred in solution. Despite the accessibility of the latter κ1-O-formate in solution, no over-reduction to a dinuclear methylene diolate was observed. Upon treatment with MeOTf, the κ1-O-formate was methylated selectively, which led to the formation of a tantalum triflate complex along with methyl formate. This is a rare example in which a value-added oxygen-containing organic product (here HCOOMe) is released from an oxophilic early transition metal (here TaV)." @default.
- W3208788730 created "2021-11-08" @default.
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- W3208788730 date "2021-11-05" @default.
- W3208788730 modified "2023-10-03" @default.
- W3208788730 title "Selective Reduction of CO<sub>2</sub> to a Tantalum Formate Complex and Release of Methyl Formate from the Tantalum(V) Center" @default.
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- W3208788730 doi "https://doi.org/10.1021/acs.inorgchem.1c02913" @default.
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