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- W3208982142 abstract "Herein, we report an unprecedented regiospecific oxidative Mizoroki-Heck type reaction for the synthesis of α -difluoromethyl homoallylic alcohols. The reaction shows broad substrate scopes and high functional group tolerance. Late-stage functionalization of complex biologically active molecules demonstrates the synthetic potential of this transformation. Mechanistic study supports the involvement of MnBr 2 catalyzed radical 1,2-silyl transfer. A regiospecific oxidative Mizoroki-Heck type reaction for the synthesis of ɑ -difluoromethyl homoallylic alcohols is described. Late-stage functionalization of complex biologically active molecules demonstrates the synthetic potential of this transformation." @default.
- W3208982142 created "2021-11-08" @default.
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- W3208982142 date "2022-05-01" @default.
- W3208982142 modified "2023-09-23" @default.
- W3208982142 title "MnBr2 catalyzed regiospecific oxidative Mizoroki-Heck type reaction" @default.
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- W3208982142 doi "https://doi.org/10.1016/j.cclet.2021.10.083" @default.
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