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- W3208985448 endingPage "107060" @default.
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- W3208985448 abstract "Zinc sulfide (ZnS) is an emerging alternate n-type buffer layer for the cadmium-free thin-film solar cells. The present research adopts a unique mixture of glycerol and tartaric acid for the emergence of phase-pure ZnS during pulse electrodeposition . Besides, proper optimization of pulse parameters aid in producing crystalline ZnS films with no post-deposition heat treatment. The as-deposited films exhibit cubic ZnS as confirmed from X-Ray Diffraction (XRD) and micro-Raman analyses. The optical study reveals an average transmittance of 71% in the wavelength spread of 300–900 nm with a band gap of 3.8 eV. The n-type semiconducting behavior of ZnS is affirmed from the Mott-Schottky analysis and the flat band potential is inferred to be −1.0 V vs SCE . The crystalline ZnS films produced from the economic pulse electrodeposition method devoid of heat treatment step, with their demonstration as photoanode in photoelectrochemical cells are suitable for the relevant applications. • A room temperature electrodeposition process for ZnS with better control over the morphology and composition. • Phase-pure ZnS is obtained using pulse electrodeposition with no post heat-treatment. • A novel method using a blend of organic reagents, tartaric acid and glycerol in the electrolyte." @default.
- W3208985448 created "2021-11-08" @default.
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- W3208985448 date "2021-12-01" @default.
- W3208985448 modified "2023-10-16" @default.
- W3208985448 title "Pulse electrodeposited zinc sulfide as an eco-friendly buffer layer for the cadmium-free thin-film solar cells" @default.
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- W3208985448 doi "https://doi.org/10.1016/j.spmi.2021.107060" @default.
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