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• W3209064371 abstract "Abstract Nitrile is one of the ubiquitous functional groups in natural products and polymer industry. It is often used as a versatile building block in synthetic chemistry. Classically, nitrile group is used for alpha functionalization, ortho −C−H activation and as a precursor for amine or carbonyl functionalities. With the development of various transition metal catalyzed methods, in the last two decades, nitrile group has emerged as a source of carbon synthons through C−CN bond activation despite of its high bond energy. In this review we have summarized all recent developments involving the carbon synthons arising from the cleavage of C−CN bonds. Depending on the fate of the carbon center after cleavage, all the reactions are classified in two major categories for the ease of discussion: 1) decyanation (removal of the nitrile group) and 2) decyanative functionalization (replacement of the nitrile group). Finally, current limitations in C−CN bond activation strategies and future prospects are discussed." @default.
• W3209064371 created "2021-11-08" @default.
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• W3209064371 date "2021-11-25" @default.
• W3209064371 modified "2023-10-16" @default.
• W3209064371 title "Recent Developments in Hydrodecyanation and Decyanative Functionalization Reactions" @default.
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• W3209064371 doi "https://doi.org/10.1002/ajoc.202100591" @default.
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