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- W3209380635 endingPage "1115" @default.
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- W3209380635 abstract "An uncharged, water-soluble per-ethylene-glycol pillar[5]arene derivative (1) was synthesized and its aggregation mode, host-guest chemistry in water and extraction ability was explored. Compound 1 is a liquid at room temperature; in water, limited self-aggregation occurred at high concentrations as deduced from diffusion NMR and dynamic light scattering. Compound 1 forms pseudo-rotaxane-like 1 : 1 host-guest complexes with 1,ω-di-substituted alkanes with association constants on the order of 103 -104 m-1 . Interestingly, NMR experiments showed that the guest location relative to the host ring system differs among the different complexes. In proof-of-concept experiments, compound 1 was shown to extract structurally related organic compounds from benzene into water with significant selectivity. Compound 1, which is a liquid at room temperature and has only limited interactions with its side arms, can, in principle, be regarded as a complement to or as a kind of type I porous liquid." @default.
- W3209380635 created "2021-11-08" @default.
- W3209380635 creator A5020734254 @default.
- W3209380635 creator A5028806841 @default.
- W3209380635 creator A5082727929 @default.
- W3209380635 date "2021-11-01" @default.
- W3209380635 modified "2023-10-16" @default.
- W3209380635 title "Aggregation Mode, Host‐Guest Chemistry in Water, and Extraction Capability of an Uncharged, Water‐Soluble, Liquid Pillar[5]arene Derivative" @default.
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- W3209380635 doi "https://doi.org/10.1002/open.202100206" @default.
- W3209380635 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8564886" @default.
- W3209380635 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34730286" @default.