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- W3209550304 abstract "Bare (1) and silica coated (1@SiO2) spin crossover (SCO) nanoparticles based on the polymer {[Fe(NH2Trz)3](BF4)2}n have been prepared following a water-in-oil synthetic procedure. For 1, the critical temperatures of the spin transition are TC↓ = 214.6 K and TC↑ = 220.9 K. For 1@SiO2, the abruptness of the transition is enhanced and the critical temperatures are centred at room temperature (TC↓ = 292.1 K and TC↑ = 296.3 K). An inert Re(I) complex of formula [Re(phen)(CO)3(PETES)](PF6) (phen = 1, 10-phenanthroline; PETES = 2(4-pyridylethyl)triethoxysilane) (Re) was also synthesized yielding intense green emission centred at λem = 560 nm. The grafting of this complex on the silica shell of 1@SiO2 led to a bifunctional SCO-luminescence composite (1@SiO2/Re) whose luminescence properties were tuned by the spin state switching. Temperature-variable photophysical studies showed that luminescence and spin transition were synchronized through a radiative (trivial) energy transfer mechanism between the Re(I) and the Fe(II)-LS (LS, Low Spin) centres." @default.
- W3209550304 created "2021-11-08" @default.
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- W3209550304 date "2021-01-01" @default.
- W3209550304 modified "2023-10-16" @default.
- W3209550304 title "Monitoring spin-crossover phenomena <i>via</i> Re(<scp>i</scp>) luminescence in hybrid Fe(<scp>ii</scp>) silica coated nanoparticles" @default.
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- W3209550304 doi "https://doi.org/10.1039/d1dt03334d" @default.
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