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• W3209934046 endingPage "4874" @default.
• W3209934046 startingPage "4868" @default.
• W3209934046 abstract "Abstract The reaction of the known closo ‐ruthenacarborane 3‐H‐3‐Cl‐3,3‐(PPh 3 ) 2 ‐ closo ‐3,1,2‐RuC 2 B 9 H 11 with tridentade nitrogen‐based ligands of the general formula (C 5 NH 4 CH 2 ) 2 NR (R=H, Me, Et, iPr, Bu t ) in benzene solution at 60 °C allowed us to isolate novel ruthenacarborane clusters 3,3,3‐(2’‐NC 5 H 4 CH 2 ) 2 NR‐ pseudocloso ‐3,1,2‐RuC 2 B 9 H 11 . According to the performed X‐ray study, the obtained compounds are the first examples of pseudocloso ‐metallacarboranes bearing unsubstituted C 2 B 9 2− nido ‐carborane ligand. In spite of the determined pseudocloso structure of the complexes in the solid state, the recorded 11 B{ 1 H} NMR spectra indicate that some of them are converted into the closo isomers in solution. The conducted quantum‐chemical calculations have confirmed the subtle difference between two configurations and possible rearrangement in solution. The performed electrochemical investigations show the ability of the formed ruthenacarboranes to undergo reversible oxidation to Ru(III) species." @default.
• W3209934046 created "2021-11-08" @default.
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• W3209934046 date "2021-11-18" @default.
• W3209934046 modified "2023-10-16" @default.
• W3209934046 title "Synthesis of Novel <i>Pseudocloso</i> Ruthenacarboranes based on an Unsubstituted <i>nido</i>‐C₂B₉H₁₁²⁻ Ligand" @default.
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• W3209934046 doi "https://doi.org/10.1002/ejic.202100765" @default.
• W3209934046 hasPublicationYear "2021" @default.
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