Matches in SemOpenAlex for { <https://semopenalex.org/work/W3209935714> ?p ?o ?g. }
- W3209935714 endingPage "12273" @default.
- W3209935714 startingPage "12264" @default.
- W3209935714 abstract "The pathway of activationless proton transfer induced by an electron-transfer reaction is studied theoretically. Long-range electron transfer produces highly nonequilibrium medium polarization that can drive proton transfer through an activationless transition during the process of thermalization, dynamically altering the screening of the electron-proton Coulomb interaction by the medium. The cross electron-proton reorganization energy is the main energy parameter of the theory, which exceeds in magnitude the proton-transfer reorganization energy roughly by the ratio of the electron-transfer to proton-transfer distance. This parameter, which can be either positive or negative, is related to the difference in pKa values in two electron-transfer states. The relaxation time of the medium is on the (sub)picosecond time scale, which establishes the characteristic time for activationless proton transfer. Microscopic calculations predict substantial retardation of the collective relaxation dynamics compared to the continuum estimates due to the phenomenology analogous to de Gennes narrowing. Nonequilibrium medium configuration promoting proton transfer can be induced by either thermal or photoinduced charge transfer." @default.
- W3209935714 created "2021-11-08" @default.
- W3209935714 creator A5003059556 @default.
- W3209935714 creator A5051795688 @default.
- W3209935714 date "2021-10-29" @default.
- W3209935714 modified "2023-10-02" @default.
- W3209935714 title "Electron-Induced Proton Transfer" @default.
- W3209935714 cites W1532739870 @default.
- W3209935714 cites W1966444654 @default.
- W3209935714 cites W1967728492 @default.
- W3209935714 cites W1968276670 @default.
- W3209935714 cites W1968963012 @default.
- W3209935714 cites W1970327813 @default.
- W3209935714 cites W1973747581 @default.
- W3209935714 cites W1976945994 @default.
- W3209935714 cites W1978936677 @default.
- W3209935714 cites W1981520015 @default.
- W3209935714 cites W1982265377 @default.
- W3209935714 cites W1983628450 @default.
- W3209935714 cites W1985567612 @default.
- W3209935714 cites W1986670180 @default.
- W3209935714 cites W1991875011 @default.
- W3209935714 cites W1996408951 @default.
- W3209935714 cites W1996994119 @default.
- W3209935714 cites W1999602233 @default.
- W3209935714 cites W2003316642 @default.
- W3209935714 cites W2013596909 @default.
- W3209935714 cites W2014585433 @default.
- W3209935714 cites W2016090732 @default.
- W3209935714 cites W2019692171 @default.
- W3209935714 cites W2021792392 @default.
- W3209935714 cites W2025823762 @default.
- W3209935714 cites W2027054748 @default.
- W3209935714 cites W2029060214 @default.
- W3209935714 cites W2031904472 @default.
- W3209935714 cites W2034639064 @default.
- W3209935714 cites W2046179424 @default.
- W3209935714 cites W2046679394 @default.
- W3209935714 cites W2050638713 @default.
- W3209935714 cites W2053602288 @default.
- W3209935714 cites W2055442639 @default.
- W3209935714 cites W2056768042 @default.
- W3209935714 cites W2073464189 @default.
- W3209935714 cites W2073936935 @default.
- W3209935714 cites W2074768610 @default.
- W3209935714 cites W2076438562 @default.
- W3209935714 cites W2079053731 @default.
- W3209935714 cites W2079642199 @default.
- W3209935714 cites W2087840455 @default.
- W3209935714 cites W2091492487 @default.
- W3209935714 cites W2095325942 @default.
- W3209935714 cites W2098498660 @default.
- W3209935714 cites W2120300736 @default.
- W3209935714 cites W2121371032 @default.
- W3209935714 cites W2123050404 @default.
- W3209935714 cites W2124129640 @default.
- W3209935714 cites W2127737840 @default.
- W3209935714 cites W2141298570 @default.
- W3209935714 cites W2151343379 @default.
- W3209935714 cites W2161749517 @default.
- W3209935714 cites W2163482010 @default.
- W3209935714 cites W2314524195 @default.
- W3209935714 cites W2326203395 @default.
- W3209935714 cites W2614884730 @default.
- W3209935714 cites W2838544110 @default.
- W3209935714 cites W2891748764 @default.
- W3209935714 cites W2897621609 @default.
- W3209935714 cites W2920832935 @default.
- W3209935714 cites W2937103177 @default.
- W3209935714 cites W2955051470 @default.
- W3209935714 cites W2966630788 @default.
- W3209935714 cites W3012159850 @default.
- W3209935714 cites W3015198088 @default.
- W3209935714 cites W3084390532 @default.
- W3209935714 cites W3085346646 @default.
- W3209935714 cites W3118324056 @default.
- W3209935714 cites W3154702255 @default.
- W3209935714 cites W3202672901 @default.
- W3209935714 cites W4210858769 @default.
- W3209935714 cites W4211091797 @default.
- W3209935714 cites W788427216 @default.
- W3209935714 doi "https://doi.org/10.1021/acs.jpcb.1c06949" @default.
- W3209935714 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34714656" @default.
- W3209935714 hasPublicationYear "2021" @default.
- W3209935714 type Work @default.
- W3209935714 sameAs 3209935714 @default.
- W3209935714 citedByCount "4" @default.
- W3209935714 countsByYear W32099357142022 @default.
- W3209935714 countsByYear W32099357142023 @default.
- W3209935714 crossrefType "journal-article" @default.
- W3209935714 hasAuthorship W3209935714A5003059556 @default.
- W3209935714 hasAuthorship W3209935714A5051795688 @default.
- W3209935714 hasConcept C110010208 @default.
- W3209935714 hasConcept C120665830 @default.
- W3209935714 hasConcept C121332964 @default.
- W3209935714 hasConcept C123669783 @default.
- W3209935714 hasConcept C147120987 @default.
- W3209935714 hasConcept C147789679 @default.