FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3209987986> ?p ?o ?g. }

• W3209987986 endingPage "18288" @default.
• W3209987986 startingPage "18279" @default.
• W3209987986 abstract "Penta-twinned metal nanowires are finding widespread application in existing and emerging technologies. However, little is known about their growth mechanisms. We probe the origins of chloride- and alkylamine-mediated, solution-phase growth of penta-twinned Cu nanowires from first-principles using multiscale theory. Using quantum density functional theory (DFT) calculations, we characterize the binding and surface diffusion of Cu atoms on chlorine-covered Cu(100) and Cu(111) surfaces. We find stronger binding and slower diffusion of Cu atoms on chlorinated Cu(111) than on chlorinated Cu(100), which is a reversal of the trend for bare Cu surfaces. We also probe interfacet diffusion and find that this proceeds faster from Cu(100) to Cu(111) than the reverse. Using the DFT rates for hopping between individual sites at Ångstrom scales, we calculate coarse-grained, interfacet rates for nanowires of various lengths─up to hundreds of micrometers─and diameters in the 10 nm range. We predict nanowires with aspect ratios of ∼100, based on surface diffusion alone. We also account for the influence of a self-assembled alkylamine layer that covers most of the {100} facets, but is absent or thin and disordered on the {111} facets and in an end zone near the {100}/{111} boundary. With an end zone, we predict a wide range of nanowire aspect ratios in the experimental ranges. Our work reveals the mechanisms by which a halide─chloride─promotes the growth of high-aspect-ratio nanowires." @default.
• W3209987986 created "2021-11-08" @default.
• W3209987986 creator A5025697929 @default.
• W3209987986 creator A5048397226 @default.
• W3209987986 creator A5068546520 @default.
• W3209987986 date "2021-11-05" @default.
• W3209987986 modified "2023-10-10" @default.
• W3209987986 title "Solution-Phase Growth of Cu Nanowires with Aspect Ratios Greater Than 1000: Multiscale Theory" @default.
• W3209987986 cites W1887161270 @default.
• W3209987986 cites W1966317751 @default.
• W3209987986 cites W1968663830 @default.
• W3209987986 cites W1968733407 @default.
• W3209987986 cites W1970127494 @default.
• W3209987986 cites W1971520976 @default.
• W3209987986 cites W1979544533 @default.
• W3209987986 cites W1981368803 @default.
• W3209987986 cites W2013963844 @default.
• W3209987986 cites W2033892347 @default.
• W3209987986 cites W2036113194 @default.
• W3209987986 cites W2044591029 @default.
• W3209987986 cites W2048126143 @default.
• W3209987986 cites W2049913136 @default.
• W3209987986 cites W2051700545 @default.
• W3209987986 cites W2058856853 @default.
• W3209987986 cites W2066656069 @default.
• W3209987986 cites W2070240428 @default.
• W3209987986 cites W2078167911 @default.
• W3209987986 cites W2079105963 @default.
• W3209987986 cites W2083222334 @default.
• W3209987986 cites W2086513155 @default.
• W3209987986 cites W2087698390 @default.
• W3209987986 cites W2093082302 @default.
• W3209987986 cites W2122427541 @default.
• W3209987986 cites W2131376182 @default.
• W3209987986 cites W2142431757 @default.
• W3209987986 cites W2149678884 @default.
• W3209987986 cites W2230666274 @default.
• W3209987986 cites W2283717796 @default.
• W3209987986 cites W2317086064 @default.
• W3209987986 cites W2318345902 @default.
• W3209987986 cites W2320407333 @default.
• W3209987986 cites W2325474597 @default.
• W3209987986 cites W2328700926 @default.
• W3209987986 cites W2417925642 @default.
• W3209987986 cites W2478079221 @default.
• W3209987986 cites W2552263228 @default.
• W3209987986 cites W2567639195 @default.
• W3209987986 cites W2755929852 @default.
• W3209987986 cites W2796331253 @default.
• W3209987986 cites W2886878416 @default.
• W3209987986 cites W2897750622 @default.
• W3209987986 cites W2920817892 @default.
• W3209987986 cites W2921605855 @default.
• W3209987986 cites W2951396280 @default.
• W3209987986 cites W2968854388 @default.
• W3209987986 cites W3008991718 @default.
• W3209987986 cites W3011267543 @default.
• W3209987986 cites W3094075726 @default.
• W3209987986 cites W3107441809 @default.
• W3209987986 cites W3111168773 @default.
• W3209987986 cites W3111206080 @default.
• W3209987986 cites W3116371514 @default.
• W3209987986 cites W3118340810 @default.
• W3209987986 cites W3126924651 @default.
• W3209987986 cites W3149289900 @default.
• W3209987986 cites W3156445131 @default.
• W3209987986 cites W3184308131 @default.
• W3209987986 doi "https://doi.org/10.1021/acsnano.1c07425" @default.
• W3209987986 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34739221" @default.
• W3209987986 hasPublicationYear "2021" @default.
• W3209987986 type Work @default.
• W3209987986 sameAs 3209987986 @default.
• W3209987986 citedByCount "13" @default.
• W3209987986 countsByYear W32099879862022 @default.
• W3209987986 countsByYear W32099879862023 @default.
• W3209987986 crossrefType "journal-article" @default.
• W3209987986 hasAuthorship W3209987986A5025697929 @default.
• W3209987986 hasAuthorship W3209987986A5048397226 @default.
• W3209987986 hasAuthorship W3209987986A5068546520 @default.
• W3209987986 hasConcept C121332964 @default.
• W3209987986 hasConcept C147597530 @default.
• W3209987986 hasConcept C147789679 @default.
• W3209987986 hasConcept C150394285 @default.
• W3209987986 hasConcept C152365726 @default.
• W3209987986 hasConcept C15696416 @default.
• W3209987986 hasConcept C159467904 @default.
• W3209987986 hasConcept C171250308 @default.
• W3209987986 hasConcept C171560689 @default.
• W3209987986 hasConcept C178790620 @default.
• W3209987986 hasConcept C179104552 @default.
• W3209987986 hasConcept C185592680 @default.
• W3209987986 hasConcept C191897082 @default.
• W3209987986 hasConcept C192562407 @default.
• W3209987986 hasConcept C44280652 @default.
• W3209987986 hasConcept C544153396 @default.
• W3209987986 hasConcept C69357855 @default.
• W3209987986 hasConcept C74214498 @default.
• W3209987986 hasConcept C8010536 @default.

• next