FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3210090123> ?p ?o ?g. }

• W3210090123 endingPage "8545" @default.
• W3210090123 startingPage "8534" @default.
• W3210090123 abstract "Cooperative interactions are responsible for the useful properties of spin crossover (SCO) materials─large hysteresis windows, critical temperatures near room temperature, and abrupt transitions─with hybrid framework materials exhibiting the greatest cooperativity and hysteresis of all SCO systems. However, little is known about the chemical origin of cooperativity in frameworks. Here, we present a combined experimental–computational approach for identifying the origin of cooperativity in the metal–organic framework (MOF) Fe(1,2,3-triazolate)2 (Fe(TA)2), which exhibits the largest known hysteresis window of all SCO materials and unusually high transition temperatures, as a roadmap for understanding the manipulation of SCO behavior in general. Variable-temperature vibrational spectroscopy provides evidence that “soft modes” associated with dynamic metal–linker bonding trigger the cooperative SCO transition. Thermodynamic analysis also confirms a cooperativity magnitude much larger than those of other SCO systems, while electron density calculations of Fe(TA)2 support previous theoretical predictions that large cooperativity arises in materials where SCO produces considerable differences in metal–ligand bond polarities between different spin states. Taken together, this combined experimental–computational study provides a microscopic basis for understanding cooperative magnetism and highlights the important role of dynamic bonding in the functional behavior of framework materials." @default.
• W3210090123 created "2021-11-08" @default.
• W3210090123 creator A5010225069 @default.
• W3210090123 creator A5015309142 @default.
• W3210090123 creator A5017253631 @default.
• W3210090123 creator A5049835404 @default.
• W3210090123 creator A5059293160 @default.
• W3210090123 creator A5080462756 @default.
• W3210090123 date "2021-10-29" @default.
• W3210090123 modified "2023-10-02" @default.
• W3210090123 title "Cooperativity and Metal–Linker Dynamics in Spin Crossover Framework Fe(1,2,3-triazolate)₂" @default.
• W3210090123 cites W1132259061 @default.
• W3210090123 cites W1949504902 @default.
• W3210090123 cites W1970642387 @default.
• W3210090123 cites W1971471404 @default.
• W3210090123 cites W1981368803 @default.
• W3210090123 cites W1982432013 @default.
• W3210090123 cites W1983468448 @default.
• W3210090123 cites W1983769027 @default.
• W3210090123 cites W1985613222 @default.
• W3210090123 cites W1992373770 @default.
• W3210090123 cites W1994880295 @default.
• W3210090123 cites W1997884116 @default.
• W3210090123 cites W2000781323 @default.
• W3210090123 cites W2005613727 @default.
• W3210090123 cites W2007395042 @default.
• W3210090123 cites W2012378360 @default.
• W3210090123 cites W2014850613 @default.
• W3210090123 cites W2028464689 @default.
• W3210090123 cites W2031246159 @default.
• W3210090123 cites W2040795315 @default.
• W3210090123 cites W2043922851 @default.
• W3210090123 cites W2053225929 @default.
• W3210090123 cites W2061396943 @default.
• W3210090123 cites W2062095590 @default.
• W3210090123 cites W2064807125 @default.
• W3210090123 cites W2070352050 @default.
• W3210090123 cites W2073378050 @default.
• W3210090123 cites W2084361772 @default.
• W3210090123 cites W2088506585 @default.
• W3210090123 cites W2091787878 @default.
• W3210090123 cites W2098001657 @default.
• W3210090123 cites W2098817582 @default.
• W3210090123 cites W2139044350 @default.
• W3210090123 cites W2139668109 @default.
• W3210090123 cites W2143753629 @default.
• W3210090123 cites W2143997640 @default.
• W3210090123 cites W2162254408 @default.
• W3210090123 cites W2313942694 @default.
• W3210090123 cites W2317865481 @default.
• W3210090123 cites W2328371807 @default.
• W3210090123 cites W2736396882 @default.
• W3210090123 cites W2766764461 @default.
• W3210090123 cites W2792657057 @default.
• W3210090123 cites W2806061319 @default.
• W3210090123 cites W2900801715 @default.
• W3210090123 cites W2937847232 @default.
• W3210090123 cites W2944314913 @default.
• W3210090123 cites W2962899444 @default.
• W3210090123 cites W3029533202 @default.
• W3210090123 cites W3040903451 @default.
• W3210090123 cites W3043095642 @default.
• W3210090123 cites W3096275222 @default.
• W3210090123 cites W3159386160 @default.
• W3210090123 cites W3164287501 @default.
• W3210090123 cites W3166257885 @default.
• W3210090123 cites W4205757075 @default.
• W3210090123 doi "https://doi.org/10.1021/acs.chemmater.1c03143" @default.
• W3210090123 hasPublicationYear "2021" @default.
• W3210090123 type Work @default.
• W3210090123 sameAs 3210090123 @default.
• W3210090123 citedByCount "11" @default.
• W3210090123 countsByYear W32100901232022 @default.
• W3210090123 countsByYear W32100901232023 @default.
• W3210090123 crossrefType "journal-article" @default.
• W3210090123 hasAuthorship W3210090123A5010225069 @default.
• W3210090123 hasAuthorship W3210090123A5015309142 @default.
• W3210090123 hasAuthorship W3210090123A5017253631 @default.
• W3210090123 hasAuthorship W3210090123A5049835404 @default.
• W3210090123 hasAuthorship W3210090123A5059293160 @default.
• W3210090123 hasAuthorship W3210090123A5080462756 @default.
• W3210090123 hasConcept C106773901 @default.
• W3210090123 hasConcept C121332964 @default.
• W3210090123 hasConcept C123299182 @default.
• W3210090123 hasConcept C159467904 @default.
• W3210090123 hasConcept C161790260 @default.
• W3210090123 hasConcept C166014724 @default.
• W3210090123 hasConcept C185592680 @default.
• W3210090123 hasConcept C26873012 @default.
• W3210090123 hasConcept C2777222292 @default.
• W3210090123 hasConcept C55493867 @default.
• W3210090123 hasConcept C8010536 @default.
• W3210090123 hasConcept C97355855 @default.
• W3210090123 hasConceptScore W3210090123C106773901 @default.
• W3210090123 hasConceptScore W3210090123C121332964 @default.
• W3210090123 hasConceptScore W3210090123C123299182 @default.
• W3210090123 hasConceptScore W3210090123C159467904 @default.
• W3210090123 hasConceptScore W3210090123C161790260 @default.

• next