FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3210246345> ?p ?o ?g. }

• W3210246345 endingPage "105363" @default.
• W3210246345 startingPage "105363" @default.
• W3210246345 abstract "The co-utilization of torrefied biomass and coal in thermochemical conversion technologies is an attractive process for the transition to green energy and chemicals. The main advantage of this process is the production of high quality oil products (closer resembling crude-oil) via synergistic interaction of primary products from the two feedstocks. These synergistic reactions often involve secondary reactions, which are promoted at high pressures. This paper reports quantitative results on the extent of synergistic reactions and the role of pressure on these reactions during co-pyrolysis of torrefied biomass and coal. Torrefied biomass was produced at 280 °C in a pilot rotary kiln and subsequently both pyrolysis and co-pyrolysis of torrefied biomass and coal was investigated in a fixed bed reactor (heating rate 7 °C/min) at temperatures of 400–600 °C and pressures of 1, 15 and 30 bar. The results show that the prior removal of hemicellulose during torrefaction maximized the potential of hydrogen transfer from cellulose/lignin-derived products to depolymerized coal fragments. Furthermore, the dehydration and condensation reactions of depolymerized fragments were suppressed during co-pyrolysis in favour of synergistic reactions between the fragments. These reactions occurred predominantly in the molten/liquid phase and their rates could be indirectly controlled by pressure (through changing the evaporation rate), resulting in substantial changes in product distribution. In the presence of coal and its released vapours, the methoxyphenols (guaiacols) and furanics yields were significantly enhanced (positive deviation >54% and >40%, respectively, compared to additive predictions), whereas the phenol yields were inhibited (negative deviation >20%); suggesting the inhibition of demethoxylation reactions in the presence of coal depolymerized fragments. To date no studies have reported the molten phase synergistic reaction pathways occurring during co-pyrolysis of torrefied biomass and coal. Based on the findings in this paper, reaction pathways were proposed for these molten phase synergistic reactions." @default.
• W3210246345 created "2021-11-08" @default.
• W3210246345 creator A5013099708 @default.
• W3210246345 creator A5045589064 @default.
• W3210246345 creator A5066715305 @default.
• W3210246345 creator A5070719783 @default.
• W3210246345 date "2022-01-01" @default.
• W3210246345 modified "2023-10-09" @default.
• W3210246345 title "Co-pyrolysis of torrefied biomass and coal: Effect of pressure on synergistic reactions" @default.
• W3210246345 cites W1574430524 @default.
• W3210246345 cites W1963680914 @default.
• W3210246345 cites W1965474475 @default.
• W3210246345 cites W1970867499 @default.
• W3210246345 cites W1973863663 @default.
• W3210246345 cites W1976308118 @default.
• W3210246345 cites W1988097195 @default.
• W3210246345 cites W1988995609 @default.
• W3210246345 cites W2008239616 @default.
• W3210246345 cites W2009462425 @default.
• W3210246345 cites W2016385502 @default.
• W3210246345 cites W2030723812 @default.
• W3210246345 cites W2040493256 @default.
• W3210246345 cites W2041052437 @default.
• W3210246345 cites W2058330204 @default.
• W3210246345 cites W2061503545 @default.
• W3210246345 cites W2065813274 @default.
• W3210246345 cites W2066285040 @default.
• W3210246345 cites W2069059903 @default.
• W3210246345 cites W2073076047 @default.
• W3210246345 cites W2090017254 @default.
• W3210246345 cites W2091498492 @default.
• W3210246345 cites W2092068786 @default.
• W3210246345 cites W2096329055 @default.
• W3210246345 cites W2097307505 @default.
• W3210246345 cites W2103199339 @default.
• W3210246345 cites W2108514988 @default.
• W3210246345 cites W2114281525 @default.
• W3210246345 cites W2120879737 @default.
• W3210246345 cites W2168187302 @default.
• W3210246345 cites W2219925702 @default.
• W3210246345 cites W2266961182 @default.
• W3210246345 cites W2314090066 @default.
• W3210246345 cites W2322360065 @default.
• W3210246345 cites W2516728091 @default.
• W3210246345 cites W2587219701 @default.
• W3210246345 cites W2663776234 @default.
• W3210246345 cites W2765743928 @default.
• W3210246345 cites W2794377213 @default.
• W3210246345 cites W2795456232 @default.
• W3210246345 cites W2902080620 @default.
• W3210246345 cites W2909812719 @default.
• W3210246345 cites W2921262956 @default.
• W3210246345 cites W2927155765 @default.
• W3210246345 cites W3014320963 @default.
• W3210246345 cites W3036978653 @default.
• W3210246345 cites W3049203224 @default.
• W3210246345 cites W3121594521 @default.
• W3210246345 cites W2461229112 @default.
• W3210246345 doi "https://doi.org/10.1016/j.jaap.2021.105363" @default.
• W3210246345 hasPublicationYear "2022" @default.
• W3210246345 type Work @default.
• W3210246345 sameAs 3210246345 @default.
• W3210246345 citedByCount "12" @default.
• W3210246345 countsByYear W32102463452022 @default.
• W3210246345 countsByYear W32102463452023 @default.
• W3210246345 crossrefType "journal-article" @default.
• W3210246345 hasAuthorship W3210246345A5013099708 @default.
• W3210246345 hasAuthorship W3210246345A5045589064 @default.
• W3210246345 hasAuthorship W3210246345A5066715305 @default.
• W3210246345 hasAuthorship W3210246345A5070719783 @default.
• W3210246345 hasBestOaLocation W32102463453 @default.
• W3210246345 hasConcept C111368507 @default.
• W3210246345 hasConcept C115540264 @default.
• W3210246345 hasConcept C127313418 @default.
• W3210246345 hasConcept C127413603 @default.
• W3210246345 hasConcept C150394285 @default.
• W3210246345 hasConcept C154877778 @default.
• W3210246345 hasConcept C161790260 @default.
• W3210246345 hasConcept C162857116 @default.
• W3210246345 hasConcept C17112743 @default.
• W3210246345 hasConcept C178790620 @default.
• W3210246345 hasConcept C185592680 @default.
• W3210246345 hasConcept C2776073808 @default.
• W3210246345 hasConcept C2779251873 @default.
• W3210246345 hasConcept C2781052789 @default.
• W3210246345 hasConcept C36759035 @default.
• W3210246345 hasConcept C37447750 @default.
• W3210246345 hasConcept C42360764 @default.
• W3210246345 hasConcept C518851703 @default.
• W3210246345 hasConcept C528095902 @default.
• W3210246345 hasConceptScore W3210246345C111368507 @default.
• W3210246345 hasConceptScore W3210246345C115540264 @default.
• W3210246345 hasConceptScore W3210246345C127313418 @default.
• W3210246345 hasConceptScore W3210246345C127413603 @default.
• W3210246345 hasConceptScore W3210246345C150394285 @default.
• W3210246345 hasConceptScore W3210246345C154877778 @default.
• W3210246345 hasConceptScore W3210246345C161790260 @default.
• W3210246345 hasConceptScore W3210246345C162857116 @default.

• next