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- W3210638942 abstract "Simultaneously generating Bi quantum dot and oxygen vacancy on Bi 2 MoO 6 nanosheets promotes the remarkably boosted photoactivity for selective oxidation of aromatic alcohols to carbonyl compounds in water medium under visible-light irradiation, mainly ascribing to the synergetic effect of Bi quantum dot and oxygen vacancy that strikingly led to the enhanced visible-light absorbance, the narrowed energy band gap, and the improved photoelectron-hole separation ability. • Hydrothermal synthesis combining post-reduction reaction route. • Simultaneously generating Bi quantum dot and oxygen vacancy on Bi 2 MoO 6 nanosheets. • Plasmonic effect of Bi quantum dot and band gap narrowing by oxygen vacancy. • Strong synergetic effect of Bi quantum dot and oxygen vacancy. • Selective alcohol oxidation by visible-light-driven photocatalysis in water medium. Constructing visible-light-driven photocatalysts with outstanding performances for selective alcohol oxidation has become a research frontier in the field of heterogeneous photocatalysis. Herein, simultaneously generating Bi quantum dot and oxygen vacancy on Bi 2 MoO 6 nanosheets, facilely achieved through a hydrothermal combining post-reduction route, has been developed to catalyze selective alcohol oxidation in D.I·H 2 O medium via visible-light-driven heterogeneous photocatalysis, actually presenting the remarkably boosted photoactivity and excellent reusability. Experimental results reveal that the remarkably boosted photoactivity can be intrinsically credited to the synergetic effect of oxygen vacancy and Bi quantum dot, strikingly leading to the narrowed band gap, the improved visible-light absorbance as well as the escalated photocharge separation capability. Impressively, its excellent reusability can be mainly correlated with Bi quantum dot strongly interacting with robust Bi 2 MoO 6 nanosheet that not only inhibits the structural collapse of Bi 2 MoO 6 nanosheet but also the leaching of Bi quantum dot, demonstrating its promising potential in future sustainable organic synthesis." @default.
- W3210638942 created "2021-11-08" @default.
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- W3210638942 date "2022-02-01" @default.
- W3210638942 modified "2023-09-29" @default.
- W3210638942 title "Simultaneously generating Bi quantum dot and oxygen vacancy on Bi2MoO6 nanosheets for boosting photocatalytic selective alcohol oxidation" @default.
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- W3210638942 doi "https://doi.org/10.1016/j.apsusc.2021.151738" @default.
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