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- W3210736433 abstract "<p>We report the hypothesis-driven development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO–N<sub>3</sub>, the radical diazidation was achieved across a broad scope of structurally diverse alkenes. Preliminary mechanistic data lend support for a dual catalytic role of the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.</p>" @default.
- W3210736433 created "2021-11-08" @default.
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- W3210736433 date "2018-12-04" @default.
- W3210736433 modified "2023-09-22" @default.
- W3210736433 title "Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes" @default.
- W3210736433 doi "https://doi.org/10.26434/chemrxiv.7413602.v1" @default.
- W3210736433 hasPublicationYear "2018" @default.
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