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• W3211117066 endingPage "15074" @default.
• W3211117066 startingPage "14957" @default.
• W3211117066 abstract "Transition-metal-catalyzed, coordination-assisted C(sp3)–H functionalization has revolutionized synthetic planning over the past few decades as the use of these directing groups has allowed for increased access to many strategic positions in organic molecules. Nonetheless, several challenges remain preeminent, such as the requirement for high temperatures, the difficulty in removing or converting directing groups, and, although many metals provide some reactivity, the difficulty in employing metals outside of palladium. This review aims to give a comprehensive overview of coordination-assisted, transition-metal-catalyzed, direct functionalization of nonactivated C(sp3)–H bonds by covering the literature since 2004 in order to demonstrate the current state-of-the-art methods as well as the current limitations. For clarity, this review has been divided into nine sections by the transition metal catalyst with subdivisions by the type of bond formation. Synthetic applications and reaction mechanism are discussed where appropriate." @default.
• W3211117066 created "2021-11-08" @default.
• W3211117066 creator A5041696931 @default.
• W3211117066 creator A5045820274 @default.
• W3211117066 creator A5058718448 @default.
• W3211117066 creator A5078657083 @default.
• W3211117066 creator A5083883404 @default.
• W3211117066 date "2021-10-29" @default.
• W3211117066 modified "2023-10-06" @default.
• W3211117066 title "Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp³)–H Bonds" @default.
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