Matches in SemOpenAlex for { <https://semopenalex.org/work/W3211175067> ?p ?o ?g. }
- W3211175067 abstract "Enantiopure monohydrosilanes are versatile chiral reagents for alcohol resolution and mechanistic investigation. Herein, we have demonstrated the asymmetric synthesis of monohydrosilanes via an intramolecular hydrosilylation strategy. This protocol is suitable for the synthesis of five- and six-membered cyclic monohydrosilanes, including a class of chiral oxasilacycles, with excellent diastereo-, regio-, and enantioselectivities. Notably, the catalyst loading could be reduced to 0.1 mol % which makes this one of the most efficient methods to access chiral monohydrosilanes. Mechanistic studies and DFT calculations indicate this Rh-catalyzed intramolecular asymmetric hydrosilylation reaction might proceed via a Chalk-Harrod mechanism, and the enantio-determining step was predicted to be oxidative addition of Si-H bond." @default.
- W3211175067 created "2021-11-08" @default.
- W3211175067 creator A5014574735 @default.
- W3211175067 creator A5017615112 @default.
- W3211175067 creator A5019954832 @default.
- W3211175067 creator A5020050122 @default.
- W3211175067 creator A5021740792 @default.
- W3211175067 creator A5049078993 @default.
- W3211175067 creator A5069099445 @default.
- W3211175067 date "2021-11-23" @default.
- W3211175067 modified "2023-10-17" @default.
- W3211175067 title "Enantioselective Synthesis of Silicon‐Stereogenic Monohydrosilanes by Rhodium‐Catalyzed Intramolecular Hydrosilylation" @default.
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