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- W32112520 abstract "Abstract Three kinds of iron catalysts are precipitated onto an Australian brown coal from an aqueous solution of FeCl 3 by using urea, Ca(OH) 2 , or NH 3 , as an additive. All the iron species on coal are found to be finely dispersed FeOOH by the XRD and ESCA measurements, and they are reduced to metallic iron during pyrolysis. The use of urea gives the highest metal dispersion. All the catalysts show gasification activities in atmospheric H 2 at 873 K and the iron catalyst prepared with urea is most effective. These observations suggest that the metal dispersion is a key factor for controlling the catalytic activity and that the present hydrogasification may proceed through a hydrogen spillover mechanism." @default.
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- W32112520 date "1993-01-01" @default.
- W32112520 modified "2023-10-16" @default.
- W32112520 title "Catalytic behavior of iron in the gasification of coal with hydogen" @default.
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- W32112520 doi "https://doi.org/10.1016/s0167-2991(08)63224-3" @default.
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