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- W3211271208 abstract "The reaction of tricyclic 5,5-benzannulated spiroketals with trifluoroacetic acid (TFA) and AlCl3 furnished benzopyranobenzopyrans, benzofuro-orthoesters, and benzofuroxanthones. Whereas the reaction of tricyclic 5,5-benzannulated spiroketals with TFA produced the pyrones, the reaction with AlCl3 furnished densely functionalized orthoesters and xanthones. The formation of these products was rationalized by fascinating mechanistic pathways involving semipinacol/α-ketol molecular rearrangements." @default.
- W3211271208 created "2021-11-08" @default.
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- W3211271208 date "2021-10-29" @default.
- W3211271208 modified "2023-09-25" @default.
- W3211271208 title "Rearrangement-Driven Molecular Diversity: Synthesis of Functionalized Pyrones, Orthoesters, and Xanthones from Spiroketals" @default.
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- W3211271208 doi "https://doi.org/10.1021/acs.orglett.1c02888" @default.
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