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- W3211271510 abstract "Two charge transfer complexes that are based on an organic basic donor, tris(hydroxymethyl)aminomethane (Tris) and two π-acceptors having acidic protons such as picric acid (PA), and chloroanilic acid (CA) were synthesized for the first time. Some physicochemical analyses including UV-vis, FT-IR and 1H-NMR were employed to investigate and confirm the proposed chemical structures of the prepared complexes. It was found that the donor–acceptor molar ratio is 1:1 for (Tris):(PA) and 1:2 for (Tris):(CA) charge transfer complexes. The formed charge transfer complexes have –NH3+ and –OH2+ ions as a result of proton transfer from acidic to basic centers. The formation constant (KCT) and molar absorptivity coefficient (eCT) were calculated from the experimental spectroscopic data. Thermodynamic studies for both charge transfer complexes showed the favorability of the complex formation." @default.
- W3211271510 created "2021-11-08" @default.
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- W3211271510 date "2016-01-01" @default.
- W3211271510 modified "2023-09-27" @default.
- W3211271510 title "Synthesis and Spectroscopic Characterizations of Tris(hydroxymethyl)aminomethane Proton Transfer Complexes with Acidic π-Acceptors" @default.
- W3211271510 hasPublicationYear "2016" @default.
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