FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3211320525> ?p ?o ?g. }

• W3211320525 endingPage "24188" @default.
• W3211320525 startingPage "24180" @default.
• W3211320525 abstract "Two isoquinoline derivatives IQ-BIM and IQ-BM with a terminal malononitrile unit, in which the double bond and single bond are used as the connecting units, respectively, are obtained simultaneously by the reaction of an isoquinoline derivative with malononitrile in the presence of a catalytic amount of triethylamine. The different connecting units show an important effect on their photophysical properties. IQ-BIM with an acceptor−π–acceptor structure exhibits an obvious aggregation-induced emission (AIE) phenomenon in the tetrahydrofuran–water mixed solvent owing to the restriction of intramolecular rotation but no obvious solvatochromic property, whereas IQ-BM with a donor−π–acceptor structure shows obvious solvatochromic and dual-state emission properties, and its emissions in the mixtures are mainly dominated by the intramolecular charge transfer effect. This result indicates that the existence of double bonds is beneficial to the occurrence of the AIE phenomenon. Although both these compounds exhibit outstanding mechanofluorochromic (MFC) activities through the crystalline-to-amorphous transition, the red shift of the fluorescence spectrum of IQ-BIM is attributed to the increased molecular conjugation, whereas that of IQ-BM is due to the generation of the excimers induced by the π–π interactions. Moreover, the former displays a higher contrast MFC phenomenon than the latter due to the looser stacking arrangement. This work gives important reference values for understanding the influence of the connecting units on the photophysical properties of fluorescent materials." @default.
• W3211320525 created "2021-11-08" @default.
• W3211320525 creator A5020346472 @default.
• W3211320525 creator A5022977934 @default.
• W3211320525 creator A5024880342 @default.
• W3211320525 creator A5024897452 @default.
• W3211320525 creator A5028984562 @default.
• W3211320525 creator A5030917048 @default.
• W3211320525 creator A5037987563 @default.
• W3211320525 creator A5053074652 @default.
• W3211320525 creator A5063164301 @default.
• W3211320525 date "2021-10-25" @default.
• W3211320525 modified "2023-10-16" @default.
• W3211320525 title "Effect of Connecting Units on Aggregation-Induced Emission and Mechanofluorochromic Properties of Isoquinoline Derivatives with Malononitrile as the Terminal Group" @default.
• W3211320525 cites W1755835286 @default.
• W3211320525 cites W1962132222 @default.
• W3211320525 cites W1981754932 @default.
• W3211320525 cites W1987613656 @default.
• W3211320525 cites W1987827133 @default.
• W3211320525 cites W2009057700 @default.
• W3211320525 cites W2019413603 @default.
• W3211320525 cites W2025492268 @default.
• W3211320525 cites W2032185182 @default.
• W3211320525 cites W2126757275 @default.
• W3211320525 cites W2134898952 @default.
• W3211320525 cites W2144906480 @default.
• W3211320525 cites W2150664885 @default.
• W3211320525 cites W2177603935 @default.
• W3211320525 cites W2263950881 @default.
• W3211320525 cites W2325144376 @default.
• W3211320525 cites W2327306990 @default.
• W3211320525 cites W2340747886 @default.
• W3211320525 cites W2395592977 @default.
• W3211320525 cites W2483513303 @default.
• W3211320525 cites W2552253098 @default.
• W3211320525 cites W2612503362 @default.
• W3211320525 cites W2624598794 @default.
• W3211320525 cites W2742451066 @default.
• W3211320525 cites W2759045686 @default.
• W3211320525 cites W2759341485 @default.
• W3211320525 cites W2800466941 @default.
• W3211320525 cites W2804611189 @default.
• W3211320525 cites W2810938061 @default.
• W3211320525 cites W2891661942 @default.
• W3211320525 cites W2911014860 @default.
• W3211320525 cites W2944106292 @default.
• W3211320525 cites W2953435602 @default.
• W3211320525 cites W2974843672 @default.
• W3211320525 cites W2981089567 @default.
• W3211320525 cites W2981252290 @default.
• W3211320525 cites W2981300655 @default.
• W3211320525 cites W2999215139 @default.
• W3211320525 cites W3004521344 @default.
• W3211320525 cites W3012249372 @default.
• W3211320525 cites W3013129163 @default.
• W3211320525 cites W3014339536 @default.
• W3211320525 cites W3022051471 @default.
• W3211320525 cites W3091812920 @default.
• W3211320525 cites W3092730278 @default.
• W3211320525 cites W3118573475 @default.
• W3211320525 cites W3119725546 @default.
• W3211320525 cites W3122276378 @default.
• W3211320525 cites W3128470507 @default.
• W3211320525 cites W3175569514 @default.
• W3211320525 cites W4251992543 @default.
• W3211320525 cites W4299496276 @default.
• W3211320525 doi "https://doi.org/10.1021/acs.jpcc.1c07410" @default.
• W3211320525 hasPublicationYear "2021" @default.
• W3211320525 type Work @default.
• W3211320525 sameAs 3211320525 @default.
• W3211320525 citedByCount "15" @default.
• W3211320525 countsByYear W32113205252022 @default.
• W3211320525 countsByYear W32113205252023 @default.
• W3211320525 crossrefType "journal-article" @default.
• W3211320525 hasAuthorship W3211320525A5020346472 @default.
• W3211320525 hasAuthorship W3211320525A5022977934 @default.
• W3211320525 hasAuthorship W3211320525A5024880342 @default.
• W3211320525 hasAuthorship W3211320525A5024897452 @default.
• W3211320525 hasAuthorship W3211320525A5028984562 @default.
• W3211320525 hasAuthorship W3211320525A5030917048 @default.
• W3211320525 hasAuthorship W3211320525A5037987563 @default.
• W3211320525 hasAuthorship W3211320525A5053074652 @default.
• W3211320525 hasAuthorship W3211320525A5063164301 @default.
• W3211320525 hasConcept C121332964 @default.
• W3211320525 hasConcept C161790260 @default.
• W3211320525 hasConcept C178790620 @default.
• W3211320525 hasConcept C185592680 @default.
• W3211320525 hasConcept C26873012 @default.
• W3211320525 hasConcept C2776923262 @default.
• W3211320525 hasConcept C2779892579 @default.
• W3211320525 hasConcept C2780513484 @default.
• W3211320525 hasConcept C32909587 @default.
• W3211320525 hasConcept C33347731 @default.
• W3211320525 hasConcept C62520636 @default.
• W3211320525 hasConcept C67218372 @default.
• W3211320525 hasConcept C75079739 @default.
• W3211320525 hasConcept C75473681 @default.
• W3211320525 hasConcept C91881484 @default.

• next