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- W3211333016 abstract "The crystallization of a local p-type ZnSb material can be deterministically tuned by doping with the n-type topological insulator Bi2Te3. Upon annealing, pure ZnSb shows a transition across three states, namely, high resistance, intermediate resistance, and low resistance. The metastable intermediate ZnSb phase has p-type conduction. Here, we find that the metastable ZnSb phase of the pure ZnSb film is significantly suppressed by Bi2Te3 doping, and the underlying conduction is changed into n-type conduction because Bi2Te3 doping induces a change in crystallization and simultaneously changes the type of crystalline phases. Nanoprecipitate formation and crystallization transition are the driving forces of the composition-dependent p–n conduction conversion. The X-ray diffraction, X-ray photoelectron and Raman spectroscopy results of the crystalline thin films suggest that the local bonding arrangement around Sb atoms changes. The Bi–Sb topological insulators are thus mainly responsible for the p–n transition and ultralow resistance shift shown by ZnSb–Bi2Te3 alloys." @default.
- W3211333016 created "2021-11-08" @default.
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- W3211333016 date "2021-11-01" @default.
- W3211333016 modified "2023-09-26" @default.
- W3211333016 title "Nanostructured ZnSb films composited with Bi2Te3 topological insulators exhibit strongly unusual p–n conduction conversion upon crystallization" @default.
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- W3211333016 doi "https://doi.org/10.1016/j.ceramint.2021.10.239" @default.
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