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- W3211420256 abstract "A novel method for P-involved heterocycle ring-closing-ring-opening rearrangement (HRR) via the Heck reaction is disclosed. The approach enables direct installation of a phosphorus-containing aryl group onto the C2 position of indole. This new rearrangement directly transforms easily prepared indole derivatives into indolyl-derived phosphonates and phosphinic acids with high yields, and many of the products are difficult to obtain by using established methods. This new HRR reaction provides an extremely simple and step-economic method to induce C-C bond formation and P-N bond cleavage for the synthesis of a variety of indolyl-type ligands." @default.
- W3211420256 created "2021-11-22" @default.
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- W3211420256 creator A5051423100 @default.
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- W3211420256 creator A5088769195 @default.
- W3211420256 date "2021-11-18" @default.
- W3211420256 modified "2023-10-01" @default.
- W3211420256 title "Heck Reaction Boosted Heterocycle Ring-Closing and Ring-Opening Rearrangement: A Strategy for the Synthesis of Indolyl-Type Ligands" @default.
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- W3211420256 doi "https://doi.org/10.1021/acs.joc.1c02117" @default.
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