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• W3211468906 abstract "A unique decarbonylation of an amino acid derivative catalytic system has been established via palladium-catalyzed C-C bond and C-N bond dual activations. By employing 8-aminoquinoline as the directing group, this transformation has been found to facilitate the high chemoselectivity to decarbonylation of amino acid derivatives rather than intramolecular deamination or cross-dehydrogenative coupling reactions. This method provides a straightforward avenue for constructing diverse functionalized amide compounds in good to excellent yields. We proposed a possible reaction pathway that may go through the C-C bond and C-N bond dual activations on the basis of the mechanistic studies." @default.
• W3211468906 created "2021-11-22" @default.
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• W3211468906 date "2021-11-16" @default.
• W3211468906 modified "2023-10-01" @default.
• W3211468906 title "Palladium-Catalyzed Decarbonylation of Amino Acid Derivatives via C–C Bond and C–N Bond Dual Activations" @default.
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• W3211468906 doi "https://doi.org/10.1021/acs.joc.1c02162" @default.
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