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• W3211580245 abstract "Direct valorization of furfural into alkyl levulinates and γ-valerolactone in primary alcohols with rare-earth metal catalysts via transfer hydrogenation was firstly reported. The effects of different rare-earth metal salts and hydrogen donors, as well as reaction parameters on the conversion of furfural were evaluated. Under optimal conditions, ca. 74 % yield of ethyl levulinate was directly produced from furfural in ethanol with YI3 as the catalyst, and more than 60 % of γ-valerolactone was yielded using YBr3. And intriguingly, it has been demonstrated that primary alcohols, such as ethanol, n-propanol etc., have superior catalytic activity than secondary alcohol due to their multiple roles in the reaction. The present study provides a green, simple and efficient way for the valorization of biomass derived furfural." @default.
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• W3211580245 date "2021-11-18" @default.
• W3211580245 modified "2023-10-06" @default.
• W3211580245 title "Direct Valorization of Furfural in Primary Alcohols Using Rare‐Earth Metal Salts" @default.
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• W3211580245 doi "https://doi.org/10.1002/slct.202103465" @default.
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