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- W3212158751 endingPage "122171" @default.
- W3212158751 startingPage "122171" @default.
- W3212158751 abstract "Bis[(2-diphenylphosphino)phenyl] ether (DPEphos) was used as chelating ligand to prepare the corresponding borohydride complex [Cu(κ2–BH4)(DPEphos)], whose structure was ascertained spectroscopically and by means of X-ray diffraction. The spectroscopic assignments related to the coordinated borohydride were confirmed by preparing the isotopologue [Cu(κ2–BD4)(DPEphos)]. Reaction of [Cu(κ2–BH4)(DPEphos)] with triflic acid afforded the dimer [Cu2(μ–BH4)(DPEphos)2][OTf] (OTf = triflate). The borohydride complexes exhibited appreciable blue emission upon excitation with UV light at room temperature. [Cu(κ2–BH4)(DPEphos)] revealed to be a suitable precursor for the preparation of luminescent heteroleptic copper(I) complexes having general formula [Cu(N^N)(DPEphos)]+ (N^N = 1,10-phenantroline, 2,9-dimethyl-1,10-phenantroline, 2,2′-bypiridine, 4,4′-dimethyl-2,2′bipyridine)." @default.
- W3212158751 created "2021-11-22" @default.
- W3212158751 creator A5012328305 @default.
- W3212158751 creator A5030215621 @default.
- W3212158751 creator A5041531483 @default.
- W3212158751 creator A5046582495 @default.
- W3212158751 date "2022-01-01" @default.
- W3212158751 modified "2023-09-23" @default.
- W3212158751 title "Preparation, reactivity and photoluminescence of copper(I) borohydride complexes with bis[(2-diphenylphosphino)phenyl] ether as chelating ligand" @default.
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- W3212158751 doi "https://doi.org/10.1016/j.jorganchem.2021.122171" @default.
- W3212158751 hasPublicationYear "2022" @default.
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