Matches in SemOpenAlex for { <https://semopenalex.org/work/W3212634961> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W3212634961 endingPage "1686" @default.
- W3212634961 startingPage "1686" @default.
- W3212634961 abstract "Abstract Here, we report on the application and characterization of parylene (poly p-xylylene) layers of nanometric thickness as a highly efficient artificial elastic SEI layer for three dimensional nanosilicon anodes. The simple deposition process creates an extremely conformal layer, even on complex 3D substrate geometries. The deposition process can be easily controlled down to thickness of 30 nm with excellent uniformity. The parylene nanothin layers were shown to be extremely stable, chemically, electrochemically and mechanically, while notably allowing the free diffusion of Li-ions into the Si underlying active layer permitted by the finite solvent diffusion through the polymeric layer. The elasticity of the organic parylene layer plays a key role in the applicability of parylene to act as an efficient artificial SEI structure, as it was shown to be capable to withstand the dramatic natural “breathing” effect of the underlying silicon nanostructures, without interruption to the active material volumetric changes, causing no additional stress on the silicon structures, while partially preventing and slowing the formation of a secondary SEI layer. Electrochemical characterization reveals that parylene VT-4 (parylene F) layer is superior to other parylene types, exhibiting >500 cycles with >75% capacity retention, dramatically improving the anode cycling life compared to bare silicon-based anodes, while not limiting the active material loading degree achievable. Importantly, the parylene layer efficacy in preserving the silicon active material is determined via 95.5% capacity retention at low c-rates. The simplicity, applicability and control of parylene deposition, along with its vast improvement of stability of bare silicon anodes, make it an excellent candidate for future applications as an efficient artificial SEI layer for next-generation silicon anodes and other active materials of interest." @default.
- W3212634961 created "2021-11-22" @default.
- W3212634961 creator A5008940499 @default.
- W3212634961 creator A5062579623 @default.
- W3212634961 creator A5081316368 @default.
- W3212634961 date "2021-10-19" @default.
- W3212634961 modified "2023-09-23" @default.
- W3212634961 title "Breathing Parylene-Based Nanothin Artificial SEI for Highly-Stable Long Life Three-Dimensional Silicon Lithium-Ion Batteries" @default.
- W3212634961 doi "https://doi.org/10.1149/ma2021-02581686mtgabs" @default.
- W3212634961 hasPublicationYear "2021" @default.
- W3212634961 type Work @default.
- W3212634961 sameAs 3212634961 @default.
- W3212634961 citedByCount "0" @default.
- W3212634961 crossrefType "journal-article" @default.
- W3212634961 hasAuthorship W3212634961A5008940499 @default.
- W3212634961 hasAuthorship W3212634961A5062579623 @default.
- W3212634961 hasAuthorship W3212634961A5081316368 @default.
- W3212634961 hasConcept C127413603 @default.
- W3212634961 hasConcept C134018914 @default.
- W3212634961 hasConcept C147789679 @default.
- W3212634961 hasConcept C159985019 @default.
- W3212634961 hasConcept C171250308 @default.
- W3212634961 hasConcept C17525397 @default.
- W3212634961 hasConcept C185592680 @default.
- W3212634961 hasConcept C192562407 @default.
- W3212634961 hasConcept C2777385008 @default.
- W3212634961 hasConcept C2777421745 @default.
- W3212634961 hasConcept C2778541603 @default.
- W3212634961 hasConcept C2779227376 @default.
- W3212634961 hasConcept C2781448156 @default.
- W3212634961 hasConcept C42360764 @default.
- W3212634961 hasConcept C49040817 @default.
- W3212634961 hasConcept C521977710 @default.
- W3212634961 hasConcept C544956773 @default.
- W3212634961 hasConcept C71924100 @default.
- W3212634961 hasConcept C89395315 @default.
- W3212634961 hasConceptScore W3212634961C127413603 @default.
- W3212634961 hasConceptScore W3212634961C134018914 @default.
- W3212634961 hasConceptScore W3212634961C147789679 @default.
- W3212634961 hasConceptScore W3212634961C159985019 @default.
- W3212634961 hasConceptScore W3212634961C171250308 @default.
- W3212634961 hasConceptScore W3212634961C17525397 @default.
- W3212634961 hasConceptScore W3212634961C185592680 @default.
- W3212634961 hasConceptScore W3212634961C192562407 @default.
- W3212634961 hasConceptScore W3212634961C2777385008 @default.
- W3212634961 hasConceptScore W3212634961C2777421745 @default.
- W3212634961 hasConceptScore W3212634961C2778541603 @default.
- W3212634961 hasConceptScore W3212634961C2779227376 @default.
- W3212634961 hasConceptScore W3212634961C2781448156 @default.
- W3212634961 hasConceptScore W3212634961C42360764 @default.
- W3212634961 hasConceptScore W3212634961C49040817 @default.
- W3212634961 hasConceptScore W3212634961C521977710 @default.
- W3212634961 hasConceptScore W3212634961C544956773 @default.
- W3212634961 hasConceptScore W3212634961C71924100 @default.
- W3212634961 hasConceptScore W3212634961C89395315 @default.
- W3212634961 hasIssue "58" @default.
- W3212634961 hasLocation W32126349611 @default.
- W3212634961 hasOpenAccess W3212634961 @default.
- W3212634961 hasPrimaryLocation W32126349611 @default.
- W3212634961 hasRelatedWork W10809561 @default.
- W3212634961 hasRelatedWork W26431758 @default.
- W3212634961 hasRelatedWork W26705850 @default.
- W3212634961 hasRelatedWork W34961998 @default.
- W3212634961 hasRelatedWork W41965405 @default.
- W3212634961 hasRelatedWork W46041475 @default.
- W3212634961 hasRelatedWork W50435232 @default.
- W3212634961 hasRelatedWork W731584 @default.
- W3212634961 hasRelatedWork W830298 @default.
- W3212634961 hasRelatedWork W8572388 @default.
- W3212634961 hasVolume "MA2021-02" @default.
- W3212634961 isParatext "false" @default.
- W3212634961 isRetracted "false" @default.
- W3212634961 magId "3212634961" @default.
- W3212634961 workType "article" @default.