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- W3212716675 abstract "Rare-earth scheelites represent a diverse family of compounds with multiple degrees of freedom, which enables the incorporation of a wide range of lanthanide color centers. Precise positioning of quantum objects is attainable by the choice of alkali cations and lattice connectivity of polyanion units. Herein, we report the structure-dependent energy transfer and lattice coupling of optical transitions in La3+- and Dy3+-containing scheelite-type double and quadruple molybdates NaLa1-xDyx(MoO4)2 and Na5La1-xDyx(MoO4)4. X-ray excitation of La3+ core states generates excited-state electron-hole pairs, which, upon thermalizing across interconnected REO8 polyhedra in double molybdates, activate a phonon-coupled excited state of Dy3+. A pronounced luminescence band is observed corresponding to optical cooling of the lattice upon preferential radiative relaxation from a hot state. In contrast, combined X-ray absorption near-edge structure and X-ray-excited optical luminescence studies reveal that such a lattice coupling mechanism is inaccessible in quadruple molybdates with a greater separation of La3+-Dy3+ centers." @default.
- W3212716675 created "2021-11-22" @default.
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- W3212716675 date "2021-11-10" @default.
- W3212716675 modified "2023-10-16" @default.
- W3212716675 title "Structure-Dependent Accessibility of Phonon-Coupled Radiative Relaxation Pathways Probed by X-ray-Excited Optical Luminescence" @default.
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- W3212716675 doi "https://doi.org/10.1021/acs.jpclett.1c03103" @default.
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