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- W321279628 abstract "The analytical signal in ac stripping coltammetry (ACSV) with mercury indicator electrodes depends on the weight of the electrolytically collected analyte at the electrode surface, the depth of the collection layer being equal to the effective diffusion-layer thickness. Replacement of the static mercury drop electrode (SMDE) by the mercury/graphite electrode (MGE) is of practical interest in that the analyte detection limit can be lowered by decreasing the colume of the telluriumcontaining polarographed solution; in addition, plant laboratories find it difficult to control the SDME uniformity. The work in this article was done on a PU-1 universal polarograph in a square-wave vol tage component mode using the three-electrode cell shown. The rotating mercury/graphite electrode is found by the authors to be superior to the static mercury drop electrode in that it can lower the detection limit for tellurium in gallium to 5.10 /SUP -7percent/ , due to the smaller volume of the polarographed solution." @default.
- W321279628 created "2016-06-24" @default.
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- W321279628 date "1986-04-01" @default.
- W321279628 modified "2023-09-25" @default.
- W321279628 title "Determination of tellurium in gallium by alternating current stripping voltammetry with a mercury/graphite electrode" @default.
- W321279628 hasPublicationYear "1986" @default.
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