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- W3212860384 abstract "A modular synthetic strategy is described whereby organometallic complexes exhibiting considerable electron-sink capacity may be assembled by using only a few simple molecular components. The Fe2(PPh2)2(CO)5 fragment was selected as a common electroactive component and was assembled around aromatic cores bearing one, two, or three isocyanide functional groups, with the resultant complexes possessing electron-sink capacities of two, four, and six electrons, respectively. The latter complex is noteworthy in that its electron-sink capacity was found to rival that of large multinuclear clusters (e.g., [Ni32C6(CO)36]6- and [Ni38Pt6(CO)48]6-), which are often considered as benchmarks of electron-sink behavior. Moreover, the modular assembly bearing three Fe2(PPh2)2(CO)5 fragments was observed to undergo reduction to a hexaanionic state over a potential window of about -1.4 to -2.1 V (vs Fc/Fc+), the relatively compressed range being attributed to potential inversions operative during the addition of the second, fourth, and sixth electrons. Such complexes may be designated noncanonical clusters because they exhibit redox properties similar to those of large multinuclear clusters yet lack the extensive network of metal-metal bonds and the condensed metallic cores that typify the latter." @default.
- W3212860384 created "2021-11-22" @default.
- W3212860384 creator A5014942412 @default.
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- W3212860384 creator A5060667791 @default.
- W3212860384 creator A5077454413 @default.
- W3212860384 date "2021-11-08" @default.
- W3212860384 modified "2023-10-17" @default.
- W3212860384 title "A Modular Strategy for Expanding Electron-Sink Capacity in Noncanonical Cluster Assemblies" @default.
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