Matches in SemOpenAlex for { <https://semopenalex.org/work/W3212880400> ?p ?o ?g. }
- W3212880400 abstract "IUPAC defines Lewis acidity as the thermodynamic tendency for Lewis pair formation. This strength property was recently specified as global Lewis acidity (gLA), and is gauged for example by the fluoride ion affinity. Experimentally, Lewis acidity is usually evaluated by the effect on a bound molecule, such as the induced 31 P NMR shift of triethylphosphine oxide in the Gutmann-Beckett (GB) method. This type of scaling was called effective Lewis acidity (eLA). Unfortunately, gLA and eLA often correlate poorly, but a reason for this is unknown. Hence, the strength and the effect of a Lewis acid are two distinct properties, but they are often granted interchangeably. The present work analyzes thermodynamic, NMR specific, and London dispersion effects on GB numbers for 130 Lewis acids by theory and experiment. The deformation energy of a Lewis acid is identified as the prime cause for the critical deviation between gLA and eLA but its correction allows a unification for the first time." @default.
- W3212880400 created "2021-11-22" @default.
- W3212880400 creator A5000849314 @default.
- W3212880400 creator A5064009313 @default.
- W3212880400 date "2021-12-08" @default.
- W3212880400 modified "2023-09-29" @default.
- W3212880400 title "What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann–Beckett Method" @default.
- W3212880400 cites W1963541791 @default.
- W3212880400 cites W1965861470 @default.
- W3212880400 cites W1970507158 @default.
- W3212880400 cites W1971262902 @default.
- W3212880400 cites W1974639070 @default.
- W3212880400 cites W1975445772 @default.
- W3212880400 cites W1978731275 @default.
- W3212880400 cites W1982214939 @default.
- W3212880400 cites W1987753766 @default.
- W3212880400 cites W1993880594 @default.
- W3212880400 cites W2004916594 @default.
- W3212880400 cites W2005877813 @default.
- W3212880400 cites W2009857519 @default.
- W3212880400 cites W2014855732 @default.
- W3212880400 cites W2018674598 @default.
- W3212880400 cites W2019705564 @default.
- W3212880400 cites W2019926612 @default.
- W3212880400 cites W2024897981 @default.
- W3212880400 cites W2027761420 @default.
- W3212880400 cites W2034151368 @default.
- W3212880400 cites W2034169410 @default.
- W3212880400 cites W2034330315 @default.
- W3212880400 cites W2034732739 @default.
- W3212880400 cites W2036743296 @default.
- W3212880400 cites W2051163372 @default.
- W3212880400 cites W2057055628 @default.
- W3212880400 cites W2070061884 @default.
- W3212880400 cites W2070996409 @default.
- W3212880400 cites W2076878961 @default.
- W3212880400 cites W2077104814 @default.
- W3212880400 cites W2078511427 @default.
- W3212880400 cites W2079049170 @default.
- W3212880400 cites W2081979752 @default.
- W3212880400 cites W2082666209 @default.
- W3212880400 cites W2087864238 @default.
- W3212880400 cites W2088645965 @default.
- W3212880400 cites W2091208014 @default.
- W3212880400 cites W2093161659 @default.
- W3212880400 cites W2097817866 @default.
- W3212880400 cites W2104276912 @default.
- W3212880400 cites W2116261340 @default.
- W3212880400 cites W2127187225 @default.
- W3212880400 cites W2127293606 @default.
- W3212880400 cites W2128608980 @default.
- W3212880400 cites W2134949102 @default.
- W3212880400 cites W2152740524 @default.
- W3212880400 cites W2170360394 @default.
- W3212880400 cites W2171916990 @default.
- W3212880400 cites W2270838075 @default.
- W3212880400 cites W2296759269 @default.
- W3212880400 cites W2313916734 @default.
- W3212880400 cites W2326988963 @default.
- W3212880400 cites W2328890485 @default.
- W3212880400 cites W2329068187 @default.
- W3212880400 cites W2330235107 @default.
- W3212880400 cites W2345860839 @default.
- W3212880400 cites W2507764024 @default.
- W3212880400 cites W2510953343 @default.
- W3212880400 cites W2536652451 @default.
- W3212880400 cites W2545797655 @default.
- W3212880400 cites W2548579624 @default.
- W3212880400 cites W26472003 @default.
- W3212880400 cites W2737353648 @default.
- W3212880400 cites W2738896003 @default.
- W3212880400 cites W2742781442 @default.
- W3212880400 cites W2746658253 @default.
- W3212880400 cites W2754013900 @default.
- W3212880400 cites W2760320302 @default.
- W3212880400 cites W2772629991 @default.
- W3212880400 cites W2782840495 @default.
- W3212880400 cites W2790927976 @default.
- W3212880400 cites W2793822271 @default.
- W3212880400 cites W2793996726 @default.
- W3212880400 cites W2794434193 @default.
- W3212880400 cites W2796787630 @default.
- W3212880400 cites W2801460324 @default.
- W3212880400 cites W2803683005 @default.
- W3212880400 cites W2811117630 @default.
- W3212880400 cites W2902946285 @default.
- W3212880400 cites W2913312214 @default.
- W3212880400 cites W2921204362 @default.
- W3212880400 cites W2938451444 @default.
- W3212880400 cites W2940880423 @default.
- W3212880400 cites W2943279811 @default.
- W3212880400 cites W2946675552 @default.
- W3212880400 cites W2950039984 @default.
- W3212880400 cites W2950345840 @default.
- W3212880400 cites W2951235754 @default.
- W3212880400 cites W2951619689 @default.
- W3212880400 cites W2955125377 @default.
- W3212880400 cites W2971077749 @default.
- W3212880400 cites W2971953721 @default.
- W3212880400 cites W2972135154 @default.