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- W3213018866 abstract "Stereoselective synthesis of bicyclo[3.3.0]octenones from chiral 1,3 enyne aldehydes bearing propargylic acetates is described. The method is based on a Au(I)-catalyzed domino sequence with concomitant transfer of chirality involving 1,3-acyloxy migration followed by Nazarov cyclization and an unprecedented aldol addition. The method furnishes densely functionalized bicyclic structures in high yields, up to 97% ee, and good diastereoselectivity." @default.
- W3213018866 created "2021-11-22" @default.
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- W3213018866 date "2019-06-10" @default.
- W3213018866 modified "2023-09-23" @default.
- W3213018866 title "Gold(I)-Catalyzed Stereoselective Cyclization of 1,3-Enyne Aldehydes by 1,3-Acyloxy Migration/Nazarov/Aldol Cascade" @default.
- W3213018866 doi "https://doi.org/10.26434/chemrxiv.8247803.v1" @default.
- W3213018866 hasPublicationYear "2019" @default.
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