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• W3213141834 abstract "N-Alkylindoles undergo Friedel-Crafts addition to aryl and secondary alkyl nitrones in the presence of trimethylsilyl trifluoromethanesulfonate and trialkylamine to produce 3-(1-(silyloxyamino)alkyl)indoles. Spontaneous conversion to bisindolyl(aryl)methanes, which is thermodynamically favored for nitrones derived from aromatic aldehydes, is suppressed under the reaction conditions. The silyloxyamino group can be deprotected with tetrabutylammonium fluoride to yield hydroxylamines." @default.
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• W3213141834 date "2021-11-15" @default.
• W3213141834 modified "2023-10-16" @default.
• W3213141834 title "Friedel–Crafts Addition of Indoles to Nitrones Promoted by Trimethylsilyl Trifluoromethanesulfonate" @default.
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• W3213141834 doi "https://doi.org/10.1021/acs.joc.1c01551" @default.
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