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- W3213194908 abstract "We present the rare existence of d5 off-centering induced weak ferroelectric polarization and demonstrate its correlation with observed magnetoelectric (ME) properties in the G type (TN ∼ 210 K) antiferromagnet Fe2TeO6 (FTO) compound. The origin of ferroelectricity (FE) is associated with both lattice and asymmetric electron density (ED) distribution around the ion cores. ME coupling is observed in magnetic field-dependent polarization, ME voltage, and magnetostrain measurements. Short-range magnetic ordering due to intrabilayer dimeric exchange coupling via the double oxygen bridged Fe–O1–Fe pathway is proposed to play a dominating role to exhibit the negative nonlinear magnetic field-dependent ME behavior at 300 K. Interbilayer exchange via Fe–O2–Fe pathways dominantly determines the hysteretic nonlinear magnetic field-dependent ME response below TN. The observed nonlinear ME coupling signifies magnetoelasticity as manifested in the temperature and magnetic field-dependent strain measurement. Hence, the rare existence of FE and magnetoelectric coupling by d5 ion is presented in FTO." @default.
- W3213194908 created "2021-11-22" @default.
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- W3213194908 date "2021-11-09" @default.
- W3213194908 modified "2023-10-16" @default.
- W3213194908 title "<i>d</i> 5 off-centering induced ferroelectric and magnetoelectric correlations in trirutile-Fe2TeO6" @default.
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- W3213194908 doi "https://doi.org/10.1063/5.0063548" @default.
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