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- W3213243313 abstract "Abstract An intramolecular 1,5‐hydride transfer reaction is observed during the synthesis of quinazolinones from anthranilamide and aliphatic dialdehyde under a mild acidic condition at room temperature. The hydride is being transferred from a dihydroquinazolinone moiety to a distal imine functional group. We proposed the hydride transfer mechanism based on the product obtained in a deuterated solvent. The influence of steric and electronic effects, and length of the dialdehyde towards the hydride transfer reaction, have been investigated. NMR and mass spectrometry are used to characterize the synthesized quinazolinones. This simple method is suitable for the preparation of a diverse array of multivalent quinazolinones." @default.
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- W3213243313 date "2021-11-10" @default.
- W3213243313 modified "2023-09-24" @default.
- W3213243313 title "Synthesis of Functionalized Quinazolinones via Acid‐Catalyzed Redox Neutral Reaction" @default.
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- W3213243313 doi "https://doi.org/10.1002/slct.202102976" @default.
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