Matches in SemOpenAlex for { <https://semopenalex.org/work/W3213302772> ?p ?o ?g. }
- W3213302772 abstract "Chemical reactivity between As and N2 , leading to the synthesis of crystalline arsenic nitride, is here reported under high pressure and high temperature conditions generated by laser heating in a diamond anvil cell. Single-crystal synchrotron X-ray diffraction at different pressures between 30 and 40 GPa provides evidence for the synthesis of a covalent compound of AsN stoichiometry, crystallizing in a cubic P21 3 space group, in which each of the two elements is single-bonded to three atoms of the other and hosts an electron lone pair, in a tetrahedral anisotropic coordination. The identification of characteristic structural motifs highlights the key role played by the directional repulsive interactions between non-bonding electron lone pairs in the formation of the AsN structure. Additional data indicate the existence of AsN at room temperature from 9.8 up to 50 GPa. Implications concern fundamental aspects of pnictogens chemistry and the synthesis of innovative advanced materials." @default.
- W3213302772 created "2021-11-22" @default.
- W3213302772 creator A5017214018 @default.
- W3213302772 creator A5018344373 @default.
- W3213302772 creator A5025150530 @default.
- W3213302772 creator A5033613288 @default.
- W3213302772 creator A5045226267 @default.
- W3213302772 creator A5047422519 @default.
- W3213302772 creator A5064084167 @default.
- W3213302772 creator A5073202290 @default.
- W3213302772 creator A5080535597 @default.
- W3213302772 creator A5082757480 @default.
- W3213302772 creator A5087662947 @default.
- W3213302772 date "2021-12-21" @default.
- W3213302772 modified "2023-10-18" @default.
- W3213302772 title "Single‐Bonded Cubic AsN from High‐Pressure and High‐Temperature Chemical Reactivity of Arsenic and Nitrogen" @default.
- W3213302772 cites W1968743155 @default.
- W3213302772 cites W1970236289 @default.
- W3213302772 cites W1970761031 @default.
- W3213302772 cites W1976206899 @default.
- W3213302772 cites W1979128621 @default.
- W3213302772 cites W1979494617 @default.
- W3213302772 cites W1982827563 @default.
- W3213302772 cites W1987183066 @default.
- W3213302772 cites W1990425052 @default.
- W3213302772 cites W1995463695 @default.
- W3213302772 cites W1997570481 @default.
- W3213302772 cites W2000660212 @default.
- W3213302772 cites W2003876096 @default.
- W3213302772 cites W2018936961 @default.
- W3213302772 cites W2025168064 @default.
- W3213302772 cites W2026648201 @default.
- W3213302772 cites W2033508566 @default.
- W3213302772 cites W2037857431 @default.
- W3213302772 cites W2038162548 @default.
- W3213302772 cites W2042047863 @default.
- W3213302772 cites W2045278603 @default.
- W3213302772 cites W2048695248 @default.
- W3213302772 cites W2050876539 @default.
- W3213302772 cites W2054980304 @default.
- W3213302772 cites W2058160071 @default.
- W3213302772 cites W2061970694 @default.
- W3213302772 cites W2065872919 @default.
- W3213302772 cites W2070071559 @default.
- W3213302772 cites W2080125974 @default.
- W3213302772 cites W2081892027 @default.
- W3213302772 cites W2082203688 @default.
- W3213302772 cites W2090895128 @default.
- W3213302772 cites W2091780235 @default.
- W3213302772 cites W2095266268 @default.
- W3213302772 cites W2096867388 @default.
- W3213302772 cites W2098007898 @default.
- W3213302772 cites W2103089301 @default.
- W3213302772 cites W2121987859 @default.
- W3213302772 cites W2140182824 @default.
- W3213302772 cites W2142461798 @default.
- W3213302772 cites W2159423201 @default.
- W3213302772 cites W2161689357 @default.
- W3213302772 cites W2325870421 @default.
- W3213302772 cites W2342905623 @default.
- W3213302772 cites W2345265920 @default.
- W3213302772 cites W2473357586 @default.
- W3213302772 cites W2511197735 @default.
- W3213302772 cites W2551323975 @default.
- W3213302772 cites W2581222906 @default.
- W3213302772 cites W2592067968 @default.
- W3213302772 cites W2593404997 @default.
- W3213302772 cites W2734437663 @default.
- W3213302772 cites W2744143941 @default.
- W3213302772 cites W2752479256 @default.
- W3213302772 cites W2760301679 @default.
- W3213302772 cites W2763776350 @default.
- W3213302772 cites W2792244761 @default.
- W3213302772 cites W2792637693 @default.
- W3213302772 cites W2883957943 @default.
- W3213302772 cites W2888417521 @default.
- W3213302772 cites W2889114852 @default.
- W3213302772 cites W2912410412 @default.
- W3213302772 cites W2943869106 @default.
- W3213302772 cites W3009901961 @default.
- W3213302772 cites W3012323013 @default.
- W3213302772 cites W3015035183 @default.
- W3213302772 cites W3033712608 @default.
- W3213302772 cites W3037590200 @default.
- W3213302772 cites W3085974557 @default.
- W3213302772 cites W3107822474 @default.
- W3213302772 cites W3108051656 @default.
- W3213302772 cites W3111083236 @default.
- W3213302772 cites W3119172760 @default.
- W3213302772 cites W3125303041 @default.
- W3213302772 cites W3128921873 @default.
- W3213302772 cites W3180426847 @default.
- W3213302772 cites W3213302772 @default.
- W3213302772 cites W4248441797 @default.
- W3213302772 cites W4254300567 @default.
- W3213302772 cites W4298471718 @default.
- W3213302772 doi "https://doi.org/10.1002/anie.202114191" @default.
- W3213302772 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34797602" @default.
- W3213302772 hasPublicationYear "2021" @default.
- W3213302772 type Work @default.