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• W3213306568 endingPage "18543" @default.
• W3213306568 startingPage "18529" @default.
• W3213306568 abstract "The sterically demanding carbene ITr (N,N'-bis(triphenylmethyl)imidazolylidene) was used as a ligand for the preparation of luminescent copper(I) complexes of the type [(ITr)Cu(R-pyridine/R'-quinoline)]BF4 (R = H, 4-CN, 4-CHO, 2,6-NH2, and R' = 8-Cl, 6-Me). The selective formation of linear, bis(coordinated) complexes was observed for a series of pyridine and quinoline derivatives. Only in the case of 4-cyanopyridine a one-dimensional coordination polymer was formed, in which the cyano group of the cyanopyridine ligand additionally binds to another Cu atom in a bridging manner, thus leading to a trigonal planar coordination environment. In contrast, employing sterically less demanding monotrityl-substituted carbene 3, no (NHC)Cu-pyridine complexes could be prepared. Instead, a bis-carbene complex [(3)2Cu]PF6 was obtained which showed no luminescence. All linear pyridine/quinoline coordinated complexes show weak emission in solution but intense blue to orange luminescence doped with 10% in PMMA films and in the solid state either from triplet excited states with unusually long lifetimes of up to 4.8 ms or via TADF with high radiative rate constants of up to 1.7 × 105 s-1 at room temperature. Combined density functional theory and multireference configuration interaction calculations have been performed to rationalize the involved photophysics of these complexes. They reveal a high density of low-lying electronic states with mixed MLCT, LLCT, and LC character where the electronic structures of the absorbing and emitting state are not necessarily identical." @default.
• W3213306568 created "2021-11-22" @default.
• W3213306568 creator A5015588368 @default.
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• W3213306568 creator A5055140196 @default.
• W3213306568 creator A5058295720 @default.
• W3213306568 creator A5067709926 @default.
• W3213306568 date "2021-11-18" @default.
• W3213306568 modified "2023-09-30" @default.
• W3213306568 title "Linear Carbene Pyridine Copper Complexes with Sterically Demanding <i>N</i>,<i>N</i>′-Bis(trityl)imidazolylidene: Syntheses, Molecular Structures, and Photophysical Properties" @default.
• W3213306568 cites W189827329 @default.
• W3213306568 cites W1899556128 @default.
• W3213306568 cites W1963871974 @default.
• W3213306568 cites W1973036992 @default.
• W3213306568 cites W1978098294 @default.
• W3213306568 cites W1981368803 @default.
• W3213306568 cites W1982356449 @default.
• W3213306568 cites W2002965181 @default.
• W3213306568 cites W2005113566 @default.
• W3213306568 cites W2008423326 @default.
• W3213306568 cites W2010604975 @default.
• W3213306568 cites W2014438322 @default.
• W3213306568 cites W2016727079 @default.
• W3213306568 cites W2017908410 @default.
• W3213306568 cites W2023271753 @default.
• W3213306568 cites W2041977650 @default.
• W3213306568 cites W2051285866 @default.
• W3213306568 cites W2056815813 @default.
• W3213306568 cites W2069974308 @default.
• W3213306568 cites W207396953 @default.
• W3213306568 cites W2078877422 @default.
• W3213306568 cites W2093456310 @default.
• W3213306568 cites W2103607851 @default.
• W3213306568 cites W2106127272 @default.
• W3213306568 cites W2116327492 @default.
• W3213306568 cites W2126383912 @default.
• W3213306568 cites W2131019432 @default.
• W3213306568 cites W2133747421 @default.
• W3213306568 cites W2141985614 @default.
• W3213306568 cites W2149749873 @default.
• W3213306568 cites W2159291597 @default.
• W3213306568 cites W2200284193 @default.
• W3213306568 cites W2261736669 @default.
• W3213306568 cites W2313282880 @default.
• W3213306568 cites W2325339364 @default.
• W3213306568 cites W2328884557 @default.
• W3213306568 cites W2345313355 @default.
• W3213306568 cites W2397667823 @default.
• W3213306568 cites W2413618376 @default.
• W3213306568 cites W2439056241 @default.
• W3213306568 cites W2464723524 @default.
• W3213306568 cites W2493041787 @default.
• W3213306568 cites W2538163741 @default.
• W3213306568 cites W2557781407 @default.
• W3213306568 cites W2561517259 @default.
• W3213306568 cites W2606624135 @default.
• W3213306568 cites W2734899409 @default.
• W3213306568 cites W2738720408 @default.
• W3213306568 cites W2754630493 @default.
• W3213306568 cites W2765836845 @default.
• W3213306568 cites W2767427249 @default.
• W3213306568 cites W2767983041 @default.
• W3213306568 cites W2774897524 @default.
• W3213306568 cites W2794655937 @default.
• W3213306568 cites W2883031457 @default.
• W3213306568 cites W2884367745 @default.
• W3213306568 cites W2890449841 @default.
• W3213306568 cites W2896476735 @default.
• W3213306568 cites W2897491328 @default.
• W3213306568 cites W2898118198 @default.
• W3213306568 cites W2908776697 @default.
• W3213306568 cites W2911951534 @default.
• W3213306568 cites W2911992229 @default.
• W3213306568 cites W2937099227 @default.
• W3213306568 cites W2944049918 @default.
• W3213306568 cites W2949754030 @default.
• W3213306568 cites W2995073254 @default.
• W3213306568 cites W2996913916 @default.
• W3213306568 cites W3002425492 @default.
• W3213306568 cites W3017009502 @default.
• W3213306568 cites W3085581608 @default.
• W3213306568 cites W3104722516 @default.
• W3213306568 cites W3117497405 @default.
• W3213306568 cites W4212980050 @default.
• W3213306568 cites W4247431709 @default.
• W3213306568 cites W4292053748 @default.
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• W3213306568 doi "https://doi.org/10.1021/acs.inorgchem.1c03082" @default.
• W3213306568 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34793149" @default.
• W3213306568 hasPublicationYear "2021" @default.
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