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• W3213561692 startingPage "18094" @default.
• W3213561692 abstract "An aromatic tricoordinated organo B(III) complex of benzitriphyrin(2.1.1) was synthesized by treating the nonaromatic phlorin analogue of meso-fused benzitriphyrin(2.1.1) with BCl3 in triethylamine/toluene and refluxing for 2 h. The X-ray structure revealed that B(III) was in a trigonal-planar geometry and was coordinated to two nitrogen atoms and one carbon. Insertion of the small B(III) ion into the meso-fused phlorin analogue resulted in transforming the nonaromatic phlorin analogue to an aromatic B(III) benzitriphyrin(2.1.1) complex. Spectral and electrochemical studies supported the aromatic nature of the B(III) complex of benzitriphyrin(2.1.1). Theoretical studies supported the major contribution of the 18π delocalization pathway toward the aromatic nature of the B(III) meso-fused benzitriphyrin(2.1.1) in comparison to the 22π delocalization pathway. The B(III) benzitriphyrin(2.1.1) complex acts as a specific colorimetric and fluorogenic F-/CN- ion sensor." @default.
• W3213561692 created "2021-11-22" @default.
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• W3213561692 date "2021-11-09" @default.
• W3213561692 modified "2023-10-18" @default.
• W3213561692 title "Synthesis, Structure, Spectral, and Anion Sensing Studies of an Aromatic <i>meso</i>-Fused Boron(III) Benzitriphyrin(2.1.1) Complex" @default.
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• W3213561692 doi "https://doi.org/10.1021/acs.inorgchem.1c02713" @default.
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