Matches in SemOpenAlex for { <https://semopenalex.org/work/W3213649904> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W3213649904 abstract "Abstract Hydrogen bonding is a phenomenon of paramount importance in room-temperature ionic liquids. The presence or absence of the hydrogen bond drastically alternates self-diffusion, shear viscosity, phase transition points, and other key properties of a pure substance. For certain applications, the presence of cation-anion hydrogen bonding is undesirable. In the present paper, we investigate perspectives of removing the hydrogen...fluorine interionic attraction in the imidazolium borates, the strongest non-covalent interaction in this type of system. Chemical modification of the tetrafluoroborate anion not only eliminates hydrogen bonding but also changes the most thermodynamically preferable orientation of the cation in the vicinity of the anion. Although the most acidic hydrogen atom of the imidazole ring remains the paramount electrophilic center of the cation, it does not engender a strong electrostatically driven coordination pattern with the properly modified anions. The reported new physical insights help compose more robust ionic liquids and tune solvation properties of the imidazolium-based RTILs." @default.
- W3213649904 created "2021-11-22" @default.
- W3213649904 creator A5049029786 @default.
- W3213649904 date "2021-11-15" @default.
- W3213649904 modified "2023-09-24" @default.
- W3213649904 title "Elimination of Interionic Hydrogen Bonding in The Imidazolium-Based Ionic Liquids" @default.
- W3213649904 cites W1989521241 @default.
- W3213649904 cites W2004612046 @default.
- W3213649904 cites W2012812438 @default.
- W3213649904 cites W2023271753 @default.
- W3213649904 cites W2029667189 @default.
- W3213649904 cites W2050818594 @default.
- W3213649904 cites W2059097678 @default.
- W3213649904 cites W2070094805 @default.
- W3213649904 cites W2073685932 @default.
- W3213649904 cites W2076736605 @default.
- W3213649904 cites W2086957099 @default.
- W3213649904 cites W2281557914 @default.
- W3213649904 cites W2321168889 @default.
- W3213649904 cites W2329559460 @default.
- W3213649904 cites W2601081289 @default.
- W3213649904 cites W2730450144 @default.
- W3213649904 cites W2805649650 @default.
- W3213649904 cites W2902375021 @default.
- W3213649904 cites W2911364526 @default.
- W3213649904 cites W2958917345 @default.
- W3213649904 cites W2993800614 @default.
- W3213649904 cites W3000358634 @default.
- W3213649904 cites W3100259867 @default.
- W3213649904 cites W3119325342 @default.
- W3213649904 cites W3137099364 @default.
- W3213649904 cites W3165802656 @default.
- W3213649904 cites W999925234 @default.
- W3213649904 doi "https://doi.org/10.21203/rs.3.rs-1061337/v1" @default.
- W3213649904 hasPublicationYear "2021" @default.
- W3213649904 type Work @default.
- W3213649904 sameAs 3213649904 @default.
- W3213649904 citedByCount "0" @default.
- W3213649904 crossrefType "posted-content" @default.
- W3213649904 hasAuthorship W3213649904A5049029786 @default.
- W3213649904 hasBestOaLocation W32136499041 @default.
- W3213649904 hasConcept C112887158 @default.
- W3213649904 hasConcept C145148216 @default.
- W3213649904 hasConcept C147597530 @default.
- W3213649904 hasConcept C148093993 @default.
- W3213649904 hasConcept C154881586 @default.
- W3213649904 hasConcept C159467904 @default.
- W3213649904 hasConcept C161790260 @default.
- W3213649904 hasConcept C178790620 @default.
- W3213649904 hasConcept C179104552 @default.
- W3213649904 hasConcept C180577832 @default.
- W3213649904 hasConcept C185592680 @default.
- W3213649904 hasConcept C2182769 @default.
- W3213649904 hasConcept C2780872544 @default.
- W3213649904 hasConcept C2780874372 @default.
- W3213649904 hasConcept C32909587 @default.
- W3213649904 hasConcept C512968161 @default.
- W3213649904 hasConceptScore W3213649904C112887158 @default.
- W3213649904 hasConceptScore W3213649904C145148216 @default.
- W3213649904 hasConceptScore W3213649904C147597530 @default.
- W3213649904 hasConceptScore W3213649904C148093993 @default.
- W3213649904 hasConceptScore W3213649904C154881586 @default.
- W3213649904 hasConceptScore W3213649904C159467904 @default.
- W3213649904 hasConceptScore W3213649904C161790260 @default.
- W3213649904 hasConceptScore W3213649904C178790620 @default.
- W3213649904 hasConceptScore W3213649904C179104552 @default.
- W3213649904 hasConceptScore W3213649904C180577832 @default.
- W3213649904 hasConceptScore W3213649904C185592680 @default.
- W3213649904 hasConceptScore W3213649904C2182769 @default.
- W3213649904 hasConceptScore W3213649904C2780872544 @default.
- W3213649904 hasConceptScore W3213649904C2780874372 @default.
- W3213649904 hasConceptScore W3213649904C32909587 @default.
- W3213649904 hasConceptScore W3213649904C512968161 @default.
- W3213649904 hasLocation W32136499041 @default.
- W3213649904 hasLocation W32136499042 @default.
- W3213649904 hasOpenAccess W3213649904 @default.
- W3213649904 hasPrimaryLocation W32136499041 @default.
- W3213649904 hasRelatedWork W1162436746 @default.
- W3213649904 hasRelatedWork W2086728523 @default.
- W3213649904 hasRelatedWork W2106377226 @default.
- W3213649904 hasRelatedWork W2146772298 @default.
- W3213649904 hasRelatedWork W2246135554 @default.
- W3213649904 hasRelatedWork W2524059099 @default.
- W3213649904 hasRelatedWork W2949854142 @default.
- W3213649904 hasRelatedWork W4223571150 @default.
- W3213649904 hasRelatedWork W4322581222 @default.
- W3213649904 hasRelatedWork W4382050462 @default.
- W3213649904 isParatext "false" @default.
- W3213649904 isRetracted "false" @default.
- W3213649904 magId "3213649904" @default.
- W3213649904 workType "article" @default.