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• W3213656376 endingPage "121987" @default.
• W3213656376 startingPage "121987" @default.
• W3213656376 abstract "One dimensional multi-fluid model is combined with a surface model to study the functionalization of polypropylene nanoparticles immersed in a repetitively pulsed low pressure air plasma. It is found that, the number densities of the charged and metastable species show periodic variations with time, whereas the concentrations of radicals increase in successive pulses. O2+ is the most important positive ion and O, OH, O3, and HO2 are the most important radicals in the functionalization of the polypropylene nanoparticle. The surface coverages of all functional groups are increased with increase in the pulse number, while the coverage of alkyl sites decreases after 200 pulses. At high pressures, the most important functional group with highest surface coverage is peroxy, followed by carbonyl, alcohol, alkoxy, and hydroperoxy. The electron number density and the incident fluxes of O2+ ions and O, OH, O3, and HO2 radicals, as well as the surface coverages of all functional groups are increased with increase in the gas pressure. Completely reverse effects were observed with increase in the gas temperature such that the incident ion and radical fluxes and all surface coverages decrease with increase in the gas temperature." @default.
• W3213656376 created "2021-11-22" @default.
• W3213656376 creator A5058775279 @default.
• W3213656376 creator A5059148463 @default.
• W3213656376 date "2022-03-01" @default.
• W3213656376 modified "2023-10-16" @default.
• W3213656376 title "Surface functionalization of polypropylene nanoparticles in a pulsed low pressure air plasma discharge" @default.
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• W3213656376 doi "https://doi.org/10.1016/j.susc.2021.121987" @default.
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