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• W3213914048 abstract "Systematic crystallization of KLn(MoO4)2 double molybdate micro/nanocrystals was achieved in this work for the family of lanthanide elements (excluding Pm) and Y via hydrothermal reaction under the optimized conditions of pH = 7, Mo/Ln molar ratio R = 5 and 200 °C, with which the intrinsic influence of lanthanide contraction on phase preference, crystallite morphology (size/shape) and crystal structure was clearly revealed. Extended synthesis also produced KLa1-xEux(MoO4)2 (KLM:xEu) and KY1-yEuy(MoO4)2 (KYM:yEu) red phosphors, and detailed spectral analysis found that the layered structure of orthorhombic KYM allows Eu3+ to have a high quenching content of ∼70 at% (y = 0.7) and higher quantum efficiency and thermal stability of luminescence. Application also indicated that the KYM:0.7Eu optimal phosphor has the potential for optical temperature sensing with the thermally coupled 5D0 and 5D1 energy levels of Eu3+." @default.
• W3213914048 created "2021-11-22" @default.
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• W3213914048 date "2021-01-01" @default.
• W3213914048 modified "2023-10-16" @default.
• W3213914048 title "KLn(MoO₄)₂ micro/nanocrystals (Ln = La–Lu, Y): systematic hydrothermal crystallization, structure, and the performance of doped Eu³⁺ for optical thermometry" @default.
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• W3213914048 doi "https://doi.org/10.1039/d1dt03642d" @default.
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