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- W3214029490 abstract "Multiresponsive materials can adapt to numerous changes in their local environment, which makes them highly valuable for various applications. Although nanostructured and polymeric multiresponsive materials are plentiful, small-molecule analogues are scarce. This work presents a compact cyclometalated platinum(II) complex that bears a crown ether cavity (18C6-PtII); the intimate ring/emitter connectivity is key to unlocking multiresponsiveness. Complex 18C6-PtII responds to (i) cationic guests, producing changes in luminescence in both solution and the solid state, (ii) solvent molecules, which perturb the packing of the complex in the solid state and cause reversible color changes, and (iii) solvent polarity, which leads to controlled aggregation. These responses may enable 18C6-PtII to function as a sensor for ions and solvents, or as a functional unit for the fabrication of hybrid supramolecular polymers and metallogels." @default.
- W3214029490 created "2021-11-22" @default.
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- W3214029490 date "2021-11-19" @default.
- W3214029490 modified "2023-09-23" @default.
- W3214029490 title "Multiresponsive Cyclometalated Crown Ether Bearing a Platinum(II) Metal Center" @default.
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- W3214029490 doi "https://doi.org/10.1021/acs.inorgchem.1c03178" @default.
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