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- W3214076549 abstract "Abstract The inhibiting effect of three prepared derivatives of 4‐(4‐Hydroxy‐3‐methoxyphenyl)‐6,7,8,9‐tetrahydro‐5H‐cyclohepta[b]pyridine on the corrosion of copper in 0.6 M NaCl (3.5%) were investigated by different electrochemical techniques and density functional theory (DFT) calculations. The electrochemical results indicated that the inhibition efficiency increased with the increase of the inhibitors concentrations till a certain concentration then nearly became constant. 4‐(4‐hydroxy‐3‐methoxyphenyl)‐2‐mercapto‐6,7,8,9‐tetrahydro‐5H‐cyclohepta[b]pyridine‐3‐carbonitrile ( C2 ) represented the best inhibition efficiency of 98.4% at 50 ppm. The polarization measurements revealed that the studied compounds C1‐C3 acted as mixed inhibitors. The adsorption of 2‐hydroxy‐4‐(4‐hydroxy‐3‐methoxyphenyl)‐6,7,8,9‐tetrahydro‐5H‐cyclohepta[b]pyridine‐3‐carbonitrile ( C1 ) on the copper surface obeyed Freundlich isotherm while the other two inhibitors obeyed Langmuir isotherm. Relatively, a good correlation was obtained between the observed inhibition efficiencies from one side, and the electronic and molecular descriptors from another side." @default.
- W3214076549 created "2021-11-22" @default.
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- W3214076549 date "2021-11-09" @default.
- W3214076549 modified "2023-09-26" @default.
- W3214076549 title "Evaluation of the inhibition effect of novel cyclohepta[b]pyridine derivatives for copper corrosion and theoretical calculations" @default.
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- W3214076549 doi "https://doi.org/10.1002/poc.4297" @default.
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