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- W3214193304 abstract "The rare earths (RE) based materials with large reversible magnetocaloric effects have been recently recognized as good candidates for practical cryogenic magnetic refrigeration. In this work, three RE-based quaternary silicon carbides of RECr2Si2C (RE = Gd, Tb, Dy) were synthesized and determined the crystal structure, magnetic properties, magnetic phase transition, and magnetocaloric performances. All RECr2Si2C compounds are crystallized in the carbon-filled CeMg2Si2-type crystal structure and revealed a second-order magnetic phase transition from ferromagnetic to paramagnetic without noticeable field or thermal hysteresis around the Curie temperatures (~10.9 K for GdCr2Si2C, ~16.6 K for TbCr2Si2C, and ~10.7 K for DyCr2Si2C). The magnetocaloric parameters including the maximum magnetic entropy change, temperature-averaged entropy changes with 3 K lift, as well as refrigerant capacity/relative cooling power are applied to determine the magnetocaloric performances, and the evaluated values are 21.7, 14.6 and 9.8 J/kgK, 20.97, 14.51, and 9.73 J/kgK, as well as 248.3/328.8, 302.8/393.8, and 211.3/274.9 J/kg for GdCr2Si2C, TbCr2Si2C, and DyCr2Si2C under the field change of 0–50 kOe. These results indicate that the GdCr2Si2C possesses promising magnetocaloric performances and is considerable for cryogenic magnetic refrigeration application." @default.
- W3214193304 created "2021-11-22" @default.
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- W3214193304 date "2022-03-01" @default.
- W3214193304 modified "2023-10-09" @default.
- W3214193304 title "Structural, magnetic, and cryogenic magnetocaloric properties in the quaternary rare earths (RE) based RECr2Si2C (RE = Gd, Tb, Dy) compounds" @default.
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- W3214193304 doi "https://doi.org/10.1016/j.jallcom.2021.162777" @default.
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