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- W3214225325 abstract "Cu-catalyzed N-arylation is a useful tool for the chemical modification of aromatic heterocycles. Herein, an efficient carbon-nitrogen cross-coupling of methyl 3-amino-1-benzothiophene-2-carboxylate with a range of (hetero)aryl iodides using CuI, l-proline and Cs2CO3 in dioxane at moderate temperature is described. The procedure is an extremely general, relatively cheap, and experimentally simple way to afford the N-substituted products in moderate to high yields. The structures of the new heterocyclic compounds were confirmed by NMR spectroscopy and HRMS investigation." @default.
- W3214225325 created "2021-11-22" @default.
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- W3214225325 date "2021-11-11" @default.
- W3214225325 modified "2023-10-17" @default.
- W3214225325 title "Mild Copper-Catalyzed, l-Proline-Promoted Cross-Coupling of Methyl 3-Amino-1-benzothiophene-2-carboxylate" @default.
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- W3214225325 doi "https://doi.org/10.3390/molecules26226822" @default.
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