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- W3214495817 endingPage "110861" @default.
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- W3214495817 abstract "1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) was used as organocatalyst to reinvestigate the ring-opening polymerization (ROP) of ε-caprolactone (CL) with benzyl alcohol (BnOH) initiator in bulk at 90 °C considering the unsuccessful ROP of CL at RT in previously reported publications. Kinetic study indicates that the PCLs could be well-designed with a controlled/living character of polymerization. The use of functional initiators, such as 2-hydroxyethyl methacrylate (HEMA), propargyl alcohol (PGA), 6-azido-1-hexanol (AHA) and methoxy poly(ethylene glycol) (mPEG) leads to end-functionalized PCLs. Accordingly, the block copolymerization of CL with δ-valerolactone (VL), trimethylene carbonate (TMC) and lactide (LA) successfully proceeded to give PCL-b-PVL, PCL-b-PTMC and PCL-b-PLA copolymers. Finally, the reaction mechanism was studied with DFT calculations and NMR measurements." @default.
- W3214495817 created "2021-11-22" @default.
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- W3214495817 date "2021-12-01" @default.
- W3214495817 modified "2023-10-16" @default.
- W3214495817 title "Reinvestigation of the ring-opening polymerization of ε-caprolactone with 1,8-diazacyclo[5.4.0]undec-7-ene organocatalyst in bulk" @default.
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- W3214495817 doi "https://doi.org/10.1016/j.eurpolymj.2021.110861" @default.
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