FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3214629745> ?p ?o ?g. }

• W3214629745 abstract "Abstract The studies of molecular dynamics in the vicinity of liquid–glass transition are an essential part of condensed matter physics. Various experimental techniques are usually applied to understand different aspects of molecular motions, i.e., nuclear magnetic resonance (NMR), photon correlation spectroscopy (PCS), mechanical shear relaxation (MR), and dielectric spectroscopy (DS). Universal behavior of molecular dynamics, reflected in the invariant distribution of relaxation times for different polar and weekly polar glass-formers, has been recently found when probed by NMR, PCS, and MR techniques. On the other hand, the narrow dielectric permittivity function ε*(f) of polar materials has been rationalized by postulating that it is a superposition of a Debye-like peak and a broader structural relaxation found in NMR, PCS, and MR. Herein, we show that dielectric permittivity representation ε*(f) reveals details of molecular motions being undetectable in the other experimental methods. Herein we propose a way to resolve this problem. First, we point out an unresolved Johari–Goldstein (JG) β-relaxation is present nearby the α-relaxation in these polar glass-formers. The dielectric relaxation strength of the JG β-relaxation is sufficiently weak compared to the α-relaxation so that the narrow dielectric frequency dispersion faithfully represents the dynamic heterogeneity and cooperativity of the α-relaxation. However, when the other techniques are used to probe the same polar glass-former, there is reduction of relaxation strength of α-relaxation relative to that of the JG β relaxation as well as their separation. Consequently the α relaxation appears broader in frequency dispersion when observed by PCS, NMR and MR instead of DS. The explanation is supported by showing that the quasi-universal broadened α relaxation in PCS, NMR and MR is captured by the electric modulus M *( f ) = 1/ε*( f ) representation of the dielectric measurements of polar and weakly polar glass-formers, and also M *( f ) compares favorably with the mechanical shear modulus data G *( f )." @default.
• W3214629745 created "2021-11-22" @default.
• W3214629745 creator A5039791408 @default.
• W3214629745 creator A5050513971 @default.
• W3214629745 creator A5060524035 @default.
• W3214629745 date "2021-11-12" @default.
• W3214629745 modified "2023-09-27" @default.
• W3214629745 title "Comparative analysis of dielectric, shear mechanical and light scattering response functions in polar supercooled liquids" @default.
• W3214629745 cites W1636787203 @default.
• W3214629745 cites W1873536811 @default.
• W3214629745 cites W1911036188 @default.
• W3214629745 cites W1971178430 @default.
• W3214629745 cites W1975586571 @default.
• W3214629745 cites W1977503969 @default.
• W3214629745 cites W1990140100 @default.
• W3214629745 cites W1990764465 @default.
• W3214629745 cites W1992032346 @default.
• W3214629745 cites W1996508800 @default.
• W3214629745 cites W1999706778 @default.
• W3214629745 cites W1999962145 @default.
• W3214629745 cites W1999991404 @default.
• W3214629745 cites W2003645337 @default.
• W3214629745 cites W2006009996 @default.
• W3214629745 cites W2011366326 @default.
• W3214629745 cites W2012682730 @default.
• W3214629745 cites W2013368541 @default.
• W3214629745 cites W2019149991 @default.
• W3214629745 cites W2020374293 @default.
• W3214629745 cites W2021397887 @default.
• W3214629745 cites W2025328880 @default.
• W3214629745 cites W2029748313 @default.
• W3214629745 cites W2031568080 @default.
• W3214629745 cites W2038258768 @default.
• W3214629745 cites W2043668480 @default.
• W3214629745 cites W2044374911 @default.
• W3214629745 cites W2048134794 @default.
• W3214629745 cites W2049626269 @default.
• W3214629745 cites W2050759825 @default.
• W3214629745 cites W2052135930 @default.
• W3214629745 cites W2052833913 @default.
• W3214629745 cites W2062483228 @default.
• W3214629745 cites W2064179045 @default.
• W3214629745 cites W2064252290 @default.
• W3214629745 cites W2065291811 @default.
• W3214629745 cites W2065453332 @default.
• W3214629745 cites W2068667411 @default.
• W3214629745 cites W2069874798 @default.
• W3214629745 cites W2070422047 @default.
• W3214629745 cites W2073200436 @default.
• W3214629745 cites W2074407154 @default.
• W3214629745 cites W2076643816 @default.
• W3214629745 cites W2077611579 @default.
• W3214629745 cites W2081410577 @default.
• W3214629745 cites W2087597939 @default.
• W3214629745 cites W2094314325 @default.
• W3214629745 cites W2094860569 @default.
• W3214629745 cites W2096701705 @default.
• W3214629745 cites W2169396481 @default.
• W3214629745 cites W2312434946 @default.
• W3214629745 cites W2313627868 @default.
• W3214629745 cites W2473809762 @default.
• W3214629745 cites W2538194787 @default.
• W3214629745 cites W2599040017 @default.
• W3214629745 cites W2737012845 @default.
• W3214629745 cites W2765443682 @default.
• W3214629745 cites W2899929659 @default.
• W3214629745 cites W2936757115 @default.
• W3214629745 cites W2972948797 @default.
• W3214629745 cites W2990224644 @default.
• W3214629745 cites W2991218057 @default.
• W3214629745 cites W2996629841 @default.
• W3214629745 cites W3025581780 @default.
• W3214629745 cites W3046847178 @default.
• W3214629745 cites W3086377752 @default.
• W3214629745 cites W3090543018 @default.
• W3214629745 cites W3091744653 @default.
• W3214629745 cites W4240036269 @default.
• W3214629745 cites W4250448744 @default.
• W3214629745 doi "https://doi.org/10.1038/s41598-021-01191-9" @default.
• W3214629745 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8589972" @default.
• W3214629745 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34772980" @default.
• W3214629745 hasPublicationYear "2021" @default.
• W3214629745 type Work @default.
• W3214629745 sameAs 3214629745 @default.
• W3214629745 citedByCount "8" @default.
• W3214629745 countsByYear W32146297452021 @default.
• W3214629745 countsByYear W32146297452022 @default.
• W3214629745 countsByYear W32146297452023 @default.
• W3214629745 crossrefType "journal-article" @default.
• W3214629745 hasAuthorship W3214629745A5039791408 @default.
• W3214629745 hasAuthorship W3214629745A5050513971 @default.
• W3214629745 hasAuthorship W3214629745A5060524035 @default.
• W3214629745 hasBestOaLocation W32146297451 @default.
• W3214629745 hasConcept C112964491 @default.
• W3214629745 hasConcept C121332964 @default.
• W3214629745 hasConcept C122865956 @default.
• W3214629745 hasConcept C133386390 @default.
• W3214629745 hasConcept C147597530 @default.
• W3214629745 hasConcept C147789679 @default.
• W3214629745 hasConcept C15744967 @default.

• next