Matches in SemOpenAlex for { <https://semopenalex.org/work/W3214717703> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W3214717703 abstract "The implementation of earth-abundant metals mediated chemistry is a major goal in homogeneous catalysis. Borrowing hydrogen/hydrogen autotransfer (BH/HA) reaction, as a straightforward and sustainable synthetic method, has attracted considerable attention in the development of earth-abuandant metal catalysts. Herein, we report a tungsten-catalyzed <i>N</i>-alkylation reaction of amines with primary alcohols via BH/HA. This phosphine-free W(phen)(CO)<sub>4</sub> (phen=1,10-phenthroline) system was demonstrated as a practical and easily accessible <i>in-situ</i> catalysis for a broad range of amines and alcohols (up to 49 examples, including 16 previously undisclosed products). Notably, this tungsten system can tolerate numerous functional groups, especially the challenging substrates with sterically hindered substituents, or heteroatoms. Mechanistic insights based on experimental and computational studies are also provided." @default.
- W3214717703 created "2021-11-22" @default.
- W3214717703 creator A5013199288 @default.
- W3214717703 creator A5019056615 @default.
- W3214717703 creator A5021293751 @default.
- W3214717703 creator A5022393729 @default.
- W3214717703 creator A5044294251 @default.
- W3214717703 creator A5077985811 @default.
- W3214717703 creator A5085230286 @default.
- W3214717703 date "2020-07-30" @default.
- W3214717703 modified "2023-09-25" @default.
- W3214717703 title "Tungsten-Catalyzed Direct N-Alkylation of Amines with Alcohols" @default.
- W3214717703 doi "https://doi.org/10.26434/chemrxiv.12732047.v1" @default.
- W3214717703 hasPublicationYear "2020" @default.
- W3214717703 type Work @default.
- W3214717703 sameAs 3214717703 @default.
- W3214717703 citedByCount "0" @default.
- W3214717703 crossrefType "posted-content" @default.
- W3214717703 hasAuthorship W3214717703A5013199288 @default.
- W3214717703 hasAuthorship W3214717703A5019056615 @default.
- W3214717703 hasAuthorship W3214717703A5021293751 @default.
- W3214717703 hasAuthorship W3214717703A5022393729 @default.
- W3214717703 hasAuthorship W3214717703A5044294251 @default.
- W3214717703 hasAuthorship W3214717703A5077985811 @default.
- W3214717703 hasAuthorship W3214717703A5085230286 @default.
- W3214717703 hasBestOaLocation W32147177031 @default.
- W3214717703 hasConcept C109474758 @default.
- W3214717703 hasConcept C121332964 @default.
- W3214717703 hasConcept C161790260 @default.
- W3214717703 hasConcept C164361826 @default.
- W3214717703 hasConcept C178790620 @default.
- W3214717703 hasConcept C185592680 @default.
- W3214717703 hasConcept C20950531 @default.
- W3214717703 hasConcept C21951064 @default.
- W3214717703 hasConcept C2777716191 @default.
- W3214717703 hasConcept C2780378348 @default.
- W3214717703 hasConcept C542268612 @default.
- W3214717703 hasConcept C66882249 @default.
- W3214717703 hasConcept C97355855 @default.
- W3214717703 hasConceptScore W3214717703C109474758 @default.
- W3214717703 hasConceptScore W3214717703C121332964 @default.
- W3214717703 hasConceptScore W3214717703C161790260 @default.
- W3214717703 hasConceptScore W3214717703C164361826 @default.
- W3214717703 hasConceptScore W3214717703C178790620 @default.
- W3214717703 hasConceptScore W3214717703C185592680 @default.
- W3214717703 hasConceptScore W3214717703C20950531 @default.
- W3214717703 hasConceptScore W3214717703C21951064 @default.
- W3214717703 hasConceptScore W3214717703C2777716191 @default.
- W3214717703 hasConceptScore W3214717703C2780378348 @default.
- W3214717703 hasConceptScore W3214717703C542268612 @default.
- W3214717703 hasConceptScore W3214717703C66882249 @default.
- W3214717703 hasConceptScore W3214717703C97355855 @default.
- W3214717703 hasLocation W32147177031 @default.
- W3214717703 hasOpenAccess W3214717703 @default.
- W3214717703 hasPrimaryLocation W32147177031 @default.
- W3214717703 hasRelatedWork W10160189 @default.
- W3214717703 hasRelatedWork W10371248 @default.
- W3214717703 hasRelatedWork W18411142 @default.
- W3214717703 hasRelatedWork W1914634 @default.
- W3214717703 hasRelatedWork W20572742 @default.
- W3214717703 hasRelatedWork W29478030 @default.
- W3214717703 hasRelatedWork W34823493 @default.
- W3214717703 hasRelatedWork W35300140 @default.
- W3214717703 hasRelatedWork W5439756 @default.
- W3214717703 hasRelatedWork W6619008 @default.
- W3214717703 isParatext "false" @default.
- W3214717703 isRetracted "false" @default.
- W3214717703 magId "3214717703" @default.
- W3214717703 workType "article" @default.