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• W3214741911 abstract "For the first time, an NAD+-type earth-abundant metal complex [Zn(pbn)2(H2O)](ClO4)2 (1) was found to exhibit photo-induced oxidizing ability to convert various primary and secondary alcohols to the corresponding aldehyde and ketone compounds. In addition, a two-electron-reduced Zn(II) complex [Zn(pbnH-pbnH)(ClO4)2] (1red) comprising the novel C-C coupling ligand, obtained by the photo-induced oxidation of alcohols by 1, was successfully isolated and completely characterized. We clarified that the photochemical oxidation of alcohols by 1 to produce 1red proceeds via an electron transfer followed by proton transfer mechanism as elucidated by kinetic analysis on the basis of absorption spectroscopic measurements." @default.
• W3214741911 created "2021-12-06" @default.
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• W3214741911 date "2021-01-01" @default.
• W3214741911 modified "2023-10-06" @default.
• W3214741911 title "An NAD+-type earth-abundant metal complex enabling photo-driven alcohol oxidation" @default.
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• W3214741911 doi "https://doi.org/10.1039/d1cc04665a" @default.
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