Matches in SemOpenAlex for { <https://semopenalex.org/work/W3215182206> ?p ?o ?g. }
- W3215182206 abstract "Abstract The use of nitroarenes as amino sources in synthesis is challenging. Herein is reported an unusual, straightforward, and transition metal-free method for the net [3 + 2]-cycloaddition reaction of 2-azaallyl anions with nitroarenes. The products of this reaction are diverse 2,5-dihydro-1,2,4-oxadiazoles (>40 examples, up to 95% yield). This method does not require an external reductant to reduce nitroarenes, nor does it employ nitrosoarenes, which are often used in N–O cycloadditions. Instead, it is proposed that the 2-azaallyl anions, which behave as super electron donors (SEDs), deliver an electron to the nitroarene to generate a nitroarene radical anion. A downstream 2-azaallyl radical coupling with a newly formed nitrosoarene is followed by ring closure to afford the observed products. This proposed reaction pathway is supported by computational studies and experimental evidence. Overall, this method uses readily available materials, is green, and exhibits a broad scope." @default.
- W3215182206 created "2021-12-06" @default.
- W3215182206 creator A5009988205 @default.
- W3215182206 creator A5027538058 @default.
- W3215182206 creator A5031025260 @default.
- W3215182206 creator A5035789695 @default.
- W3215182206 creator A5037620851 @default.
- W3215182206 creator A5039808795 @default.
- W3215182206 creator A5090280140 @default.
- W3215182206 date "2021-12-03" @default.
- W3215182206 modified "2023-10-18" @default.
- W3215182206 title "SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles" @default.
- W3215182206 cites W1889384145 @default.
- W3215182206 cites W1964370181 @default.
- W3215182206 cites W1966049967 @default.
- W3215182206 cites W1969480166 @default.
- W3215182206 cites W1971580515 @default.
- W3215182206 cites W1971865027 @default.
- W3215182206 cites W1975024782 @default.
- W3215182206 cites W1982854974 @default.
- W3215182206 cites W1993790852 @default.
- W3215182206 cites W1994430776 @default.
- W3215182206 cites W2002759367 @default.
- W3215182206 cites W2007974882 @default.
- W3215182206 cites W2013360324 @default.
- W3215182206 cites W2017661606 @default.
- W3215182206 cites W2022012026 @default.
- W3215182206 cites W2023765234 @default.
- W3215182206 cites W2026655781 @default.
- W3215182206 cites W2057579910 @default.
- W3215182206 cites W2057716183 @default.
- W3215182206 cites W2060783559 @default.
- W3215182206 cites W2064516222 @default.
- W3215182206 cites W2067635727 @default.
- W3215182206 cites W2067650781 @default.
- W3215182206 cites W2073189049 @default.
- W3215182206 cites W2106320907 @default.
- W3215182206 cites W2108339755 @default.
- W3215182206 cites W2109714918 @default.
- W3215182206 cites W2121523029 @default.
- W3215182206 cites W2126984719 @default.
- W3215182206 cites W2127313328 @default.
- W3215182206 cites W2130706492 @default.
- W3215182206 cites W2156322726 @default.
- W3215182206 cites W2236745200 @default.
- W3215182206 cites W2333671104 @default.
- W3215182206 cites W2386907975 @default.
- W3215182206 cites W2513584870 @default.
- W3215182206 cites W2597778753 @default.
- W3215182206 cites W2605950430 @default.
- W3215182206 cites W2610413628 @default.
- W3215182206 cites W2739347791 @default.
- W3215182206 cites W2762711912 @default.
- W3215182206 cites W2763889595 @default.
- W3215182206 cites W2800600672 @default.
- W3215182206 cites W2803501277 @default.
- W3215182206 cites W2803768523 @default.
- W3215182206 cites W2806764979 @default.
- W3215182206 cites W2895346043 @default.
- W3215182206 cites W2897492770 @default.
- W3215182206 cites W2898795701 @default.
- W3215182206 cites W2899763550 @default.
- W3215182206 cites W2908876348 @default.
- W3215182206 cites W2921330864 @default.
- W3215182206 cites W2945587946 @default.
- W3215182206 cites W2946535777 @default.
- W3215182206 cites W2949756693 @default.
- W3215182206 cites W2949870775 @default.
- W3215182206 cites W2950111453 @default.
- W3215182206 cites W2951290344 @default.
- W3215182206 cites W2954962589 @default.
- W3215182206 cites W3006699785 @default.
- W3215182206 cites W3007800716 @default.
- W3215182206 cites W3014577938 @default.
- W3215182206 cites W3031893850 @default.
- W3215182206 cites W3129124368 @default.
- W3215182206 doi "https://doi.org/10.1038/s41467-021-26767-x" @default.
- W3215182206 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34862375" @default.
- W3215182206 hasPublicationYear "2021" @default.
- W3215182206 type Work @default.
- W3215182206 sameAs 3215182206 @default.
- W3215182206 citedByCount "6" @default.
- W3215182206 countsByYear W32151822062022 @default.
- W3215182206 countsByYear W32151822062023 @default.
- W3215182206 crossrefType "journal-article" @default.
- W3215182206 hasAuthorship W3215182206A5009988205 @default.
- W3215182206 hasAuthorship W3215182206A5027538058 @default.
- W3215182206 hasAuthorship W3215182206A5031025260 @default.
- W3215182206 hasAuthorship W3215182206A5035789695 @default.
- W3215182206 hasAuthorship W3215182206A5037620851 @default.
- W3215182206 hasAuthorship W3215182206A5039808795 @default.
- W3215182206 hasAuthorship W3215182206A5090280140 @default.
- W3215182206 hasBestOaLocation W32151822061 @default.
- W3215182206 hasConcept C134121241 @default.
- W3215182206 hasConcept C147597530 @default.
- W3215182206 hasConcept C161790260 @default.
- W3215182206 hasConcept C178790620 @default.
- W3215182206 hasConcept C185592680 @default.
- W3215182206 hasConcept C191897082 @default.
- W3215182206 hasConcept C192562407 @default.