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- W3215339616 abstract "For Table of Contents Only: Self-assembly strategy provides significant improvements of 1 O 2 production for photosensitizers owing to its promoted solubility, light absorption and ISC capability. Under white light (80 mW/cm 2 ), degradation of toxic sulfur mustard simulants (CEES) to nontoxic CEESO has been achieved with an extremely fast reaction rate 90 s and 100% selectivity. • Supramolecular triangle was synthesized by a facile single-step self-assembly process. • Supramolecular self-assembly strategy improved the efficiency of singlet oxygen ( 1 O 2 ) production. • The degradation of sulfur mustard simulant (2-chloroethyl ethyl sulfide, CEES) was obviously enhanced. (RuBpy 3 ) 2+ -bisterpyridine-based metallacycle T photosensitizer has been prepared by a facile single-step self-assembly process. Supramolecular self-assembly strategy greatly improved metallacycle T ’s photosensitized ability due to its enhanced light-harvesting capability, smaller energy gap ( Δ E ST ) between lowest excited singlet state (S1) and lowest excited triplet state (T1) along with excellent solubility which exhibiting higher efficiency for singlet oxygen ( 1 O 2 ) production than the ligand L and its pendant [(RuBpy 3 ) 2+ ·2PF 6 – ]. In the practical photo-driven degradation of sulfur mustard simulant (2-chloroethyl ethyl sulfide, CEES), full conversion of toxic CEES to nontoxic CEESO has been achieved by metallacycle T with an extremely fast lifetime of 90 s (half lifetime t 1/2 = 25 s) and 100% selectivity (without formation of highly toxic CEESO 2 ), while ligand L and [(RuBpy 3 ) 2+ ·2PF 6 – ] needed 130 s and 330 s, respectively. This study demonstrated terpyridine-based novel supermolecules can serve as efficient scaffolds for effective enhancement of photosensitization." @default.
- W3215339616 created "2021-12-06" @default.
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- W3215339616 date "2022-01-01" @default.
- W3215339616 modified "2023-10-18" @default.
- W3215339616 title "(RuBpy3)2+-bisterpyridinyl Triangle Promoted Singlet Oxygen (1O2) Photosensitization for Fast Oxidation of Sulfur Mustard Simulant" @default.
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- W3215339616 doi "https://doi.org/10.1016/j.inoche.2021.109090" @default.
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